GCMS surrogate recovery data for PAHs, sample 3731, Mar 2002

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Library Search Compound Report « Data File : C:\MSDCHEM\1\DATA\031202\3731.D Vial: 57 Acq On : 13 Mar 2002 2:46 am Operator: McLean Sample : SAMPLE 3731 2/19/02 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C: \DATABASE\WILEY7N. L Peak Number 4 Benzo[ghi]perylene $$ Benzo... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

37.38 2.39 ug/L 910889 Perylene-d12 34.19

Hit# of 5 Tentati tf> MW MolForm CAS# Qual

1 Benzo[ghi]perylene $$ Benzo-1,12.- 276 C22H12 000191-24-2 2Benzoighliperylene -------- 276 C22H12 000191-24-2 3 Benzo[ghi]perylene (CAS) $$ 1,12... 276 C22H12 000191-24-2 95 4 Dibenzo[def,mno]chrysene $$ Anth... 276 C22H12 000191-26-4 94 Abundance Scan 3782 (37.380 min): 3731.D (-) m/z 276.05 100.00% 276

5000

138 PT — 1 ! | 1 37.00 37.20 37.40 37.60 . 74 91 123 j 191207222 248 J m/z 138.10 25.30% UT I I | t >11 | I T TITT TT | r t 1 T TIT T 1 T T] T TT] TIT TT T TTTITTTIT TT r 1 T miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #221624: Benzo[ghijperylene $$ Benzo-1,12-perylene $$ 1.12... 276

5000 A--A 37.00 37.20 37.40 37.60 138 m/z 277.10 24.60%

18 50 74 91 106 123 1 158174 198 222237252 j, 0 TT i I i TTT i )i j I TTT, ill >1 I TT i TTT TT TTT TTT T TT ill TTT ) I I |*I I I J | TTT I | I TTT i i miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #221625: Benzo[ghi]perylene 276 41 TIT I’ 37.00 37.20 37.40 37.60 5000 m/z 137.10 20.91%

138 1 oL 27 50 . 74 98 ,, 123 1 , 159174 198222248 1 m/z-> 20 40 60 80 100 120 140 160 180 200 20 Abundance #221631: Benzo[ghijperylene (CAS) $$ 1,12-Benzoperylene $$... — Mr 276 37.00 37.20 37.40 37.60 m/z 274.10 19.43%

5000 138

m/z—> 0-mH — ‘1000900000807 92 112 ।, _______________ 249 '1 20 40 60 80 100 120 140 160 180 200 220 240 260 280 .. ।/11. —AA ... 11 37.00 37.20 37.40 37.60

3731.D 5080302.M Fri Mar 15 14:27:02 2002 Page 6

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