GCMS comments for sample AD29785 detecting phthalate, Jan 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C: \HPCHEM\1\DATA\DEC1401\29785.D Vial: 5 Acq On 15 Dec 2001 6:26 am Operator: 209 GALOS Sample : gems scan 12/10 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanone, 1,1,1-trichloro- Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

7.74 0.55 ug/1 133037 1,4-Dichlorobenzene-d4 11.68

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2 -Propanone, 1,1,1-trichloro- 160 C3H3C130 000918-00-3 45 2 N-Acetylpyrrolidone 127 C6H9NO2 000932-17-2 7 3 2-Acetylthiazole 127 C5H5NOS 024295-03-2 7 4 2-Propanone, 1,1-dichloro-_______ 126 C3H4C120______ 000513-88-2 7 Abundance Scan 293 (7.737 min): 29785.D (-) m/ z 4 .95 100.00% 4)3

5000-

35 88 97LL 821100 119125 7.40 7.60 7.80 8.00 - ,1 . 49 .63 69 ' i ' ' ■ ■ 1 • ■ • 'i ■ 11 ... m/ z 124.85 12.58% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12247: 2-Propanone, 1,1.1-trichloro- 4)3

5000- 7.40 7.60 7.80 8.00______

15 m/ z 96.95 8.26% | 35 49 85 97 117 125 m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #4732: N-Acetylpyrrolidone 43 1 7.40 7.60 7.80 8.00______ 5000- m/ z 81.85 7.91% 99 127 30 56 86 T—r l ■ ■ ■ ■ । । । । i 69 II! 112 m/z--> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #4717: 2-Acetylthiazole I ' ' ' ‘ I ' ' ' ' I 43 7.40 7.60 7.80 8.00 m/ z 82.9.5 7.23% 5000 99 58 127 112 85

m/z-> • । • ■ ■ ■ । • • ■ • । 10 20 30 33 . । . | 40 1 ' 1 1 50 l60........ 70 J.... 80 90 100 110 • • i ■ ■ Th ■ ■ ■ 120 130 7.40 7.60

29785.D GCMS1126.M Fri Dec 28 13:19:59 2001 Page 2

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