GCMS comments for sample AD29785 detecting phthalate, Jan 2002

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Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\DEC1401\29785.D Vial: 5 Acq On : 15 Dec 2001 6:26 am Operator: 209 GALOS Sample : gems scan 12/10 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 N-Ethylformamide Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.60 3.36 ug/1 817391 1,4-Dichlorobenzene-d4 11.68

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 N-Ethylformamide 73 C3H7NO 000627-45-2 9 2 1,3-Dioxolane, 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 3 1,3-Dioxolane, 2-methyl- 88 C4H802 000497-26-7 5 4 Ether 74 C4H10O 000060-29-7 4 {Abundance Scan 278 (7.599 min): 29785.D (-) m/ z 73.0.0 100.00% 73

5000 43 7.20 7.40 7.60 7.80 — 35 1 1 50 55 67, | |......... 87 ............. 103............... ■ ■ i ■ ' ' 1 i 1 ■ • i ■ m/ z 43.00 27.20%

C m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #292: N-Ethylformamide 30 73

5000 r I ' ' ' ' I 1 r1 • I 1 1 58 7.20 7.40 7.60 7.80 8.00 44 m/z 41.0.0 10.05% 15 Tmmmpppr — 4 ■ l • ■ m/z—> 10 20 30 40 I50 60 70 80 90 100 110 120 Abundance #49423: 1,3-Dioxolane, 2-(3-bromo-5,5,5-trichloro-2,2-dimet 73 =TR—ommme 7.20 7.40 7.60 7.80 8.00 5000- m/z 45.05 9.84% 45 36 55 67 -n , , , rrpi . . । i . : . । . , , . । > i-, । , . TTI ..................... 109 115, m/z-> 10 20 30 4 50 60 70 80 90 100 110 120 Abundance #62902: 1,3-Dioxolane, 2-methyl- —IIm—Pmer 73 7.20 7.40 7.60 7.80 8.00 m/z 71.00 6.80% 5000 43

58 27 87 -...........-........................ — > । • ■ ■ ■ । > -.......... ■ ■ i ■ ' miz-> 10 20 30 40 50 60 70 80 90 100 .110 120 7.20 7.40 7.60 7.80 8.00

29785.D GCMS1126.M Fri Dec 28 13:19:54 2001 Page 1

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