GCMS analysis comments for sample AD29464 with phthalate detection, Jan

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Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\DEC1301\29518.D Vial: 10 Acq On : 13 Dec 2001 6:40 pm Operator: 209 GALOS Sample : gems scan 12/6 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************** * ********** Peak Number 1 N-Ethylformamide Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

7.59 2.60 ug/1 1000800 1,4-Dichlorobenzene-d4 . 11.67

Hit# of 5 Ten tive ID MW MolForm CAS# Qual

1 N-Ethylforma de 73 C3H7NO 000627-45-2 9 2 1,3-Dioxola: 2-(3-bromo-5,5,5-tri 352 C10H16BrC13O2 000000-00-0 9 3 Silane, te amethyl- 88 C4H12Si 000075-76-3 9 4 Butane, 2 ethoxy-2-methyl- 102 C6H140 000994-05-8 9 Abundance Scan 278 (7.595 min): 29518.D (-) 73 m/ z 72.j^l00.00% 5000 43 7.20 7.40 7.60 7.80 8.00 ■ । ■ • • • । ■ 37, |, I _ _ 5561 67, 4... 67 ... 103...... Fdnnmnmmnmnannmm m/z 42.95 27.85% m/z-> 10 20 30 40 .50 60 70 80 90 100 110 120 Abundance #292: N-Ethylformamide 1 30 73

5000- i 1 ' 58 7.20 7.40 7.60 7.80 8 00 44 m/z 44.95 10.13%

m/z-> Abundance

5000- 10 r ’ , .I 20 30 ■ I, mmpr 40 50 60 70

73 80 90 100 #49423: 1,3-Dioxolane, 2-(3-bromo-5,5,5-trichloro-2,2-dimet 110 120

7.20 m/ Z 1-13 ' T TI—mnnnnnu 7.40 41.05 L 7.60 7.80 10.05% 8.00

45 36 55 67 109 115 ■ i ■ ■ ■ ■ । ■ i > ■ > ■ l ■ ■ • > i • > ’ • • i • ■ “. ’ i . ■ ■ . i ■ ■ • ■ i ■ > . • i .

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #845: Silane, tetramethyl- ■ i • ■ • • i > - 73 7.20 7.40 7.60 7.80 8.00 m/z 71.00 5.89% 5000

45 15 31 m/z--> 'i 1 11 10 20 30 — 40 ... 50 55—— — 60 —70 I 80 88 90 1 ■ ' i ' ' ■ ' i ' ' ‘ ' i ' ■ ' ' i ' ■ ■ ' i ' ' 100 110 120 7.20 7.40 7.60 7.80 8.00

29518.D GCMS1126.M Fri Dec 21 13:12:56 2001 Page 1

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