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GCMS analysis results for sample AD29670, Jan 2002

Machine-extracted title · confidence 100%

GCMS analysis report for sample AD29670 listing unknown compounds and surrogate recovery data from January 28, 2002.

NYC-WTC_000036842–000036859

Folder label: “GCMS X 12/7/01 A 1/2/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\JAN0302\29670.D Vial: 15 Acq On 4 Jan 2002 12 :13 am Operator: 209 GALOS Sample gems scan 12/7 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT. P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 10 Benzoic acid, 2,5-bis(trimethy Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.27 ug/1 152636 Phenanthrene-dl0 24.81

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, ,5-bis(trimethylsilo 370 C16H30O4Si3 003618-20-0 43 2 N- (Trifluorac etyl)-0,0',O"-tris(tri 495 C20H36F3NO4Si3 000000-00-0 37 3 N- (Trifluoroacetyl) -0,0' ,0' ’-tris,(t 481 C19H34F3NO4Si3 000000-00-0 37 4. Benzoic acid, 2,4-bis[(trimethylsil 370 C16H30O4Si3 010586-16-0 32 Abundance Scan 1916 (22.637 min): 29670.D (-) m/ z 73.00 100.00%| 73

5000 147 355 -.... — 221 281 j i 45 191 | 249 . j , 327 k 401 22.40 22.60 22.80 23.00 117 : —(+ PI 1 * L m/ z 147.00 25.61% m/z-> 50 100 150 200 250 300 350 400 450 500 Abundance #73978: Benzoic acid, 2,5-bis(trimethylsiloxy)-, trimethyls I 73 355

5000- 22.40 22.60 22.80 23.00 45 m/ Z 355.05 23.22% J....... .147 179 223 267 297... |_ m/z-> 50 100 150 200 250 300 350 400 450 500 Abundance #58807: N-(Trifluoracetyl)-O,O'.O"-tris(trirnetliylsilyl)epin 73 355 4 22.40 22.60 22.80 23.00 5000 m/z 221.05 16.85%

45 1. 140 184 281 | 480 ■ ' i ' ■ ■ ■ i ' m/z-> 50 100 150 200 250 300 350 400 450 500 Abundance #58326: N-(Trifluoroacetyl)-O,O',O"-tris(trimethylsilyl)no A I ‘ ' I ' ' 73 22.40 22.60 22.80 23.00 355 m/ Z 281.00 14.17% 5000

45 | 1, 126147 193265 376 481 TB miz-> 50 100 150 200 250 300 350 400 450 500 22.40 22.60 22.80 23.00

29670.D GCMS1126.M Wed Jan 16 14:51:11 2002 Page 10

NYC-WTC_000036858

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NYC-WTC_000036858Source: NYC Law Department, mirrored locally

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