GCMS comments for sample AD28597, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2901\28597.D Vial: 46 Acq On : 30 Nov 2001 7:11 am Operator: 209 GALOS Sample : 11/23 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 1,4-Dichlorobenzene-d4 Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 11.57 0.53 ug/1 126117 1,4-Dichlorobenzene-d4 11.69 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1, 4-Dichlorobenzene-d4 150 C6C12D4 003855-82-1 53 2 Benzene-1,23,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 35 3 4-Amino-2 chlorobenzonitrile 152 C7H5C1N21 020925-27-3 10 4 Benzaldehyde, 2-hydroxy-3-methoxy- 152 C8H803 000148-53-8 10 Abundance “ Scan 710 (11.565 min): 28597.D (-) m/z 149.90 100.00% 150

5000- 115 78 52 11.20 1140 11.60 11.80 ' ' ' 38 45 ,1, , 66 ,1 1.87103 111 ‘ -111 ■ •'' i' ■ ■ ■ i •' ■ ' i' ' 1 ■ i • ■ ■ • i ■ ■ ■ ■ i ■ • m/z 151.90 60.61% mz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9593: 1,4-Dichlorobenzene-d4 150

5000- 115 1 I............... TTTT ■ 11111 78 1120 11.40 11.60 11.80 52 m/z 115.00 . 35.64%

m/z-> 35 TIpuunpt 30 40 50 ■' i' ■ ■ ■ i ■ ■ ....... ....... 1............... T"tC‘O‘TTETTICITXVIIII""IT‘‘21011 60 70 80 90 100 110 120 130 140 150 160 L— Abundance #9592: 8602606-1,2,3,4-44-, 5,6-dichloro- 150

115 11 20 1l'40 11.60 11.80....... 5000 52 78 m/z 78.05 20.56%

m/z-> Abundance 30 35 I 40 50 '' I''' ' i ' ' 60 87 I i '' ' ' i ' ■ ■ ■ i • ■' ■ i ■ ' 70 80 90 100 110 120 130 140 150 160 #10110: 4-Amino-2-chlorobenzonitrile + I— 152 1120 11.40 11.60 11.80 m/z 52.00 15.05% 5000

90 117 125 63 76 ' ■ i ■ ■ ■ ■ 11 b M 11' ■ ■ i1 ■ ■ ■ i ■11 ■ i ■ 111'1 ■ i ■'1' i'1 ’1 i • ‘ ■ ■ i ■ ■ ■ ■ i 1 —.....*PP ■' i ■ ■ m/z—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 11.20 11.40 11.60 11.80

28597.D GCMS1126.M Fri Nov 30 15:31:43 2001 Page 2

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