GCMS comments for sample AD28265, Nov 2001

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2601\28265.D Vial: 20 Acq On : 27 Nov 2001 5:17 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 1,4-Dichlorobenzene-d4 Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

11.56 0.52 ug/1 99884 1,4-Dichlorobenzene-d4 11.70

Hit# of 5 entative ID MW MolForm CAS# Qual

1 1, 4-Dichlorobenzene-d4 150 C6C12D4 003855-82-1 64 2 Benzene-1, 2,3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 37 3 Benzaldehyde, 2-hydroxy-3-methoxy- 152 C8H803 000148-53-8 10 4 Benzenamine, N-methyl-4-nitro- 152 C7H8N202 _____ 000100-15-2 9 Abundance C Scan 710 (11.560 min): 28265.D (-) ———I m/z 149.90 100.00% 150

5000 115 52 78 r i ■ ■ ■ • i ■ ' ■ ~l ■ ■ ■ ■ T ' ■ ' ’ i ■ 11.20 11.40 11.60 11.80 40 63 87 1 —........ ....... ........................ • ■ i 1 -H r 144 M -44-'I r 1’ D - m/z 151.90 66.89% mlz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9593:1,4-Dichlorobenzene-d4 150

5000 115 TT T—nn ' I ' 78 11.20 11.40 11.60 11.80 52 m/z 114.90 37.23%

miz-> 35 TIV—t, 30 40 50 ■11'1111 ■ ■ 60 70 80 । < 90 100 110 120 130 7 ।‘ i ■ < > • । • ■ ■ j ।>। ।.।. 140 I— 150 160 Abundance #9592: Benzene-1,2,3,4-d4-, 5,6-dichloro- 150 —........ - 115 11 20 11.40 11.60 11.80 5000 52 78 m/z 78.05 20.25%

m/z-> Abundance 30 35 _____ I________ ' ' i 1 ' ' ■ i ' ■ ' ' i 40 50 ■ ‘ i ' ■ ■ ■ i ■ ■ 60 70 80 90 100 87 I i ' ■'' i ' ' ' ■ i 120 130 #66892: Benzaldehyde, 2-hydroxy-3-methoxy- 110 +— 140 - 150 160 TI T ' ' T ' 1 ' ■ i ■ 152 11 20 11.40 11.60 11.80 m/z 52.00 18.29% 106 5000 53 81

m/z-> 1 1 I 'r 1 ' I 1 ' 1' I1 30 40 50 ■ ■ । 60 ■ i • ■ 70 • f ■ ■ ■ 80 90 92 11 > ■ ■ i > 100 122 —.. — 110 120 130 136 140 150 160 .....A 11.20 11.40 11.60 11.80

28265.D GCMS1126.M Wed Nov 28 11:29:17 2001 Page 1

NYC-WTC_000033832