GCMS analysis comments for sample AD28147, Dec 2001

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Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0501\28147.D Vial: 7 Acq On 5 Dec 2001 6:30 pm Operator: 209 GALOS Sample re extract Inst : GC/MS 209 Mise : Multiplr: 1.00 % MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Propanedioic acid, hexyl-, die Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

35.59 0.74 ug/1 89287 Perylene-dl2 37.12

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Propanedioic acid, hexyl-, diethyl 005398-10-7 35 244 C13H2404 2 Methyl 4-nitrophenyl sulphoxide 000940-12-5 25 185 C7H7NO3S 3 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5 240 C12H20N2O3 051209-91-7 23 4 2-Butenedigic acid (E)~, bis(2-ethy 340 C20H36O4 000141-02-6 17 Abundance Scan 3327 (35.589 min): 28147.D (-) m/z 185.10 100.00% 185 57 5000 70 43 112 83 -----PAPI 98 35.20 35.40 35.60 35.80 36.00 1.1 ii li ii!id till 125 it143 209166 281 297 , , . , 'p. ‘ t, ‘ ‘ rp । TII Hi T‘ ‘rT I | iI I — I | I I I I ! ! I I I ] ’ I ■ ' ’ • l ’ m/ z 56.95 63.84% m/z-> 20 40 __ 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #32687: Propanedioic acid, hexyl-, diethyl ester 57 70 5000 83 112 35.20 35.40 35.60 35.80 36.00

_L m/ Z 70.00 43.51% 98 — — — 199 217 TTT’ > > i ■ • ■ ■ i ■ l ■ ■ • • 11' > 11 mlz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #19102: Methyl 4-nitrophenyl sulphoxide 185 -AP —AAA 35 20 35.40 35.60 35.80 36.00 5000 170 m/z 55.00 38/81% 30 50 — 124 140 ... 163 7692 i1 ■ ■ ■ । । > ■ ■ ■ i ■ ■ ■ ■ i • • ■ • i TT m/z-> 20 Abundance 40 60 80 100 120 140 160 180 200 220 240 260 280 300 #31908: 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5,5-diethyl-1-(2- atgouuaadd wtr 185 35 20 35.40 35.60 35.80 36.00 m/z 71.00 35.33%

5000

56... ..... "

m/z-> 20 40 60 97 114 141 157170 212225 ' i 1 ' 1 1 i ' ■ ■ ■ i ■ ■ 1 r i ■ ■ ■ " i ■ ' ■ ■ i ■ ■ ■' i ' Ml! I HI ITTTII

80 100 TTT 120 140 160 180 200 220 240 260 280 300 A—4 M —4 AAAAA 35.20 35.40 35.60 35.80 36.00

28147.D GCMS1126.M Thu Dec 06 08:38:32 2001 Page 2

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