GCMS calibration table with surrogate recovery data, Feb 16, 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\FEB1502\1137.D Vial: 10 Acq On : 16 Feb 2002 12:12 am Operator: 209 GALOS Sample : gc/ms scan 1/16 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 5 3-Tsopropoxy-l, 1,1,7,7,7-hexam Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

40.77 0.46 ug/1 52964 Perylene-dl2 38.09

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-1sopropoxy-1, 1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 33 2 Ethanedioic aci bis(trimethylsily 234 C8H18O4Si2 018294-04-7 22 3 Pentanoic acid, -[ (trimethylsilyl) 262 CllH2603Si2 055887-46-2 22 4 Butanoic acid. methyl-3-[(trimeth 262CllH26O3Si2 055124-90-8 22 Abundance Scan 3892 (40.770 min): 1137.D (-) m/z 73.00 100.00% 73 147

5000 221 281 44 • ■ i ■ ■ ■ ■ i ■ • 191 253 1.327,355 429 40.40 40.60 40.80 41.00 41.20 m/z 147.00 75.41% m/z-> 50 100 150 200 250 300 450 350 500 400 550 Abundance #60503: 3-Isopropoxy-1.1,1,7.7.7-hexamethyl-3,5,5-tris(trim 73

5000 A a N ' I ‘I 147 40.40 40.60 40.80 41.00 41.20 m/z 221.05 50.49% 221 281 327 415 I 519 561 ‘‘I‘‘‘‘I‘‘*I****I*‘I*‘‘I*’’’ I’ i . । । ii . t । । । । । -r-r-T-r-r m/z-50 100 150 200 250 300 350 400 . 450 500 550 Abundance 30590. ethen 0 •: ** ■ n1 73 147

40.40 40.60 40.80 41.00 41.20 5000 m/z 281.00 26.73% 45 , 190 219 ■ ■ i ■ ‘ ■ i • ■ • ■ i ■ ‘ ■ i ‘ ■ 1 i ' ‘ 1 ■ i ' ‘ ■ i ■ ‘ ‘ i ■ 1 ■ ■ i ' ‘ ■ 1 i ■ • ■ ■ i ■ ■ m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #36156: Pentanoic acid, 2-[(trimethylsily1)oxy]-, trimethyl 73 131 40.40 40.60 40.80 41.00 41.20 m/z 207.00 22.94% 5000 wMy Mwy/ 46 205 24J ■ ‘I ■ ■ ' 'I ‘ ■ ‘ ‘ I ‘ ' I ‘ ‘ 4 ' I ‘ ' I * ‘ * I * ‘ ‘ I • ‘ ‘ ' I ' 1 1 1 I 1 1 m/z-> 50 100 150 200 250 300 350 400 450 500 550 40.40 40.60 40.80 41.00 41.20

1137.D GCMS0208.M Mon Mar 04 15:10:21 2002 Page 5

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