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GCMS calibration table for TCLP analysis, Dec 5 2001

Machine-extracted title · confidence 100%

Calibration data sheet listing standard compounds and response factors used for GCMS analysis on December 5, 2001.

NYC-WTC_000032142–000032159

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC0 5 01\26712.D Vial: 3 Acq On 5 Dec 2001 10:35 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 l-Pentene, 4-methyl- Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

5.11 1.01 ng/uL 354684 1,4-Dichlorobenzene-d4 11.86

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Pentene, 4-methyl- 84 C6H12 000691-37-2 33 2 l-Pentanol, 4-methyl- 102 C6H140 000626-89-1 33 3 1-Hexene 84 C6H12 000592-41-6 33 4 1-Butanol Abundance 74 C4H10O 000071-36-3 28 Scan 29 (5.111 min): 26712.D(4 m/z 41.05 100.00% i ! 41 I 56

5000-

71 । I I r i । i i i TT’TT 1 " »T TImm

miz-> 5 I.... 1.... 1.TT . I —3+ UM + 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 I’TTTTT'" I 100 TrT) 4.90 5.00 5.10 5.20 5.30 5.40 5.50 m/ z 56 10 77.02% Abundance #599: 1-Pentene, 4-methyl- i 43

5000- 56 TTTTTDTTT TPWTTITT 27 4.90 5.00 5.10 5.20 5.30 5.40 5.50 69 m/z 59 10 72.67% 15 84 - I''" I" " I 51. il p-rTTyTTTTrp-rTTp-rTTy I ’IT mmmmmmmm m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #63578: 1-Pentanol. 4-methyl- I 56 41 I 111 > ■ I • • ■ < 1 . ’ • ■ ■ t mP 4.90 5.00 5.10 5.20 5.30 5.40 5.50 69 5000- m/z 42.05 61.77%

; 84 i" " r " 'I'1'1 r1'1 r "' r " ■ i1 • ■ ■ i1 ■" i"111" " r ■" r "' i" " r " 'ibi i" "I"1' r'" i" “I m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #62755: 1-Hexene l1 ‘ ■ l ■ ■ ■ ■ l TTTT 41 >56 4.90 5.00 5.10 5.20 5.30 5.40 5.50 27 m/z , 43.10 60.07% 5000

m/z-> —l+ TTTTTTTTTTTTTTT " r " ■ i' 69 84

TTCT T’TUTETTT’TTNTTTTT’T’TT 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 .. W..... 4.90 5.00 5.10 5.20 5.30 5.40 5.50

26712.D NP112701.M Fri Dec 07 13:15:09 2001 Page 2

NYC-WTC_000032149

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NYC-WTC_000032149Source: NYC Law Department, mirrored locally

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