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GCMS calibration table for TCLP analysis, Dec 5 2001

Machine-extracted title · confidence 100%

Calibration data sheet listing standard compounds and response factors used for GCMS analysis on December 5, 2001.

NYC-WTC_000032142–000032159

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0501\26712.D Vial: 3 Acq On 5 Dec 2001 10:35 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title 208 625/TCLP calibration table Library C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Oxirane, 3-ethyl-2,2-dimethyl- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

5.17 1.88 ng/uL 656290 • 1,4-Dichlorobenzene-d4 11.86

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Oxirane, 3 -ethyl-2,2-dimethyl- 100 C6H120 001192-22-9 43 2 Pentane, 2 ,3- dimethyl - 100 C7H16 000565-59-3 35 3 Pentane, 2, 3-dimethyl - 100 C7H16 000565-59-3 35 4 Pentane, 2,4-dimethyl- 100 C7H16 000108-08-7 32 'Abundance Scan 36 (5.175 min): 26712.D (-) m/ z 4 .10 100.00% 41 56

5000- 71 __ 5.00 5.20 5.40 5:60

miz-> 37 TT I' " ‘ I TT] t+tt +50+ + I ” 111 100 rrtrr 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 m/z. 43.05 70.63% Abundance #1516: Oxirane, 3-ethyl-2,2-dimethyl-

5000- 31 41 59

85 m/z 5.00 W. 5.20 56.10 5.40 5.60 68.86% 71 J 100 " I" " 11 ‘IT " i" " i i" ■' i ■ "' i' " ' i i1,111'' ’m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #1597: Pentane, 2,3-dimethyl- 43 56 1 1 i 1 1 1 1 i 1 1 i 1 ddId- 5.00 5.20 5.40> 5.60 5000 m/ Z 59.10 (67.10% 27 71

85 100 TTTTTTTTTTTTTTTTTTTTTTTT << I.... J.... 1.... f.... 11.... I > I. 11 > 1111... 11 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #63430: Pentane, 2,3-dimethyl- 43 56 5.00 5.20 5.40 5.60 m/ z 42.05 56.41%

miz-> 5000-

i• i 27 11 •. ■ i ■ ■ ■ ■ । ■ i ■" ' 111 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 ............ 71

85 100 i" " r '1' I ■ " ' r "' r'" i" ' ‘ i TT Ju5.00 5.20 5.40 11 ' । ■ 5.60

26712.D NP112701.M Fri Dec 07 13:15:11 2001 Page 3

NYC-WTC_000032150

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