GCMS calibration table for TCLP analysis, Dec 5 2001

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Data File C:\HPCHEM\1\DATA\DECO5O1\26712.D Vial: 3 Acq On 5 Dec 2001 10:35 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 4 Propanoic acid, 2-methyl-, anh Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

6.11 1.07 ng/uL 373184 1,4-Dichlorobenzene-d4 11.86

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Propanoic acid 2-methyl-, anhydrid 158 C8H14O3 000097-72-3 50 2 2 -Hepten-3-ol 4,5-dimethyl- 142 C9H180 055956-37-1 38 3 Butanoic acid, anhydride 158 C8H14O3 000106-31-0 36 4 Cyclopentanol , 1-methyl- 100 C6H120 001462-03-9 9 Abundance 70 Scan 138 (6.110 min): 26712.D (-) i • 71 m/z 71.05 100.00%

5000 43

—————

m/z~> ■ ■ i ■ • ■ ■ i ■ 10 20 —su 30 40 50 60 70I ( 80 90 100 100 110 120 130 5.80 6.00 6.20 m/ z 43.10 6.40 42.47%

N Abundance #11901: Propanoic acid. 2-methyl-, anhydride 71 V 43 5000 5.80 6.00 6.20 6.40 m/ z 41.05 24.71% .......27 37 55

v. AA 1 I ' ' 1 ' I ' 1 1 ' I ' ' ' ' 1 1 ■ i ■ • 1 • i • miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #*8051: 2-Hepten-3-ol. 4,5-dimethyl- 71

5.80 6.00 6.20 6.40 5000 43 m/ z 42.10 19.62% 27 1 15 55 । 81 100 109 124 1 —p • i ■ ■ ■ ■ i ■ ■ • ■ i ■ ■ • ■ I ■ ■ ■ ■ i ■ ■ ■ ■ r ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ • i • ■ ■ ■ i ■ ■ ■ • i ■ ■ ■ ■ i • m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #11888: Butanoic acid, anhydride A 4444444 i 71 5.80 6.00 6.20 6.40 m/ Z 39.00 12.38% 43 5000- 27

। m/z-> 15 TI 10 — 60 ' i ' '' ' i '''' i ' ' ■ ' i ■ ' ' ' i ''•• I • TIT । । ।1।।' । । । । ' 20 30 40 50 60 70 80 90 100 110 120 130 M. AM 5.80 6.00 6.20 6.40

26712.D NP112701.M Fri Dec 07 13:15:13 2001 Page 4

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