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GCMS analysis results for sample AD26680, Dec 10 2001

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis of sample AD26680 identifying unknown compounds on December 10, 2001.

NYC-WTC_000032058–000032078

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0401\26680.D Vial: 3 Acq On 4 Dec 2001 12:38 pm Operator: GALOS Sample gc/ms unknown Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 9 2-Butanol, 3-methyl-, (S) - Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.15 5.14 ng/uL 1382110 1,4-Dichlorobenzene-d4 11.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butanol, 3-methyl - , (S) - 88 C5H120 001517-66-4 40 2 1,2 -Propanediol , 3-methoxy- 106 C4H10O3 000623-39-2 36 3 2,3-Butanediol 90 C4H10O2 000513-85-9 33 4 2-But ol, 3-methyl- 88 C5H120 000598-75-4 9 'Abundance Scan 251 (7.147 min): 26680.D (-) m/ z 45.05 100.00% 45

5000 - 61 73 —i. A -- — । > । । ■ ■ । । । 6.80 7.00 7.20 7.40______

m/z-> mlll 188 TT . . | TTTT । i i i I । i i > i p i ■ t । i I H । i r TTTT II | I III | I I I I | I I I I | I I I I | I I I I I I 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 207 TTTTTT m/z 43.00 65.45% Abundance #852: 2-Butanol, 3-methyl-, (S)- 45

5000 TT 6.80 7.00 7.20 7.40______ 55 73 m/z 61.10 36.95% 27 I | 1..... 87.............................................. ......................................... ' M... H i" "i ‘I"IETTOTETTTTTETT‘T‘IICIETTTUTTCTTT‘TTTT—‘TEICURTTTTT miz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 'Abundance #63660: 1,2-Propanediol, 3-methoxy- 45 - ■ > i • ■ ■ ■ । ■ 6.80 7.00 7.20 7.40 5000 75 m/ z 73.05 35.94% 31 61 15 88 TTTTTTTUTTT*TT । r 1111. > i > p ,,, p ,,, p ,,, p (, 11, H ( r111 r ■" i" r ■" r "' r ■ "i"' m/z--> 1p 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance ' ' #917: 2,3-Butanediol A............ /............... i 45 6.80 7.00 7.20 7.40______ m/z 44.0,5 13.86% 5000

29 57

miz-> 19J 111111 —l .1 75 90TTEET"TOIUTTTTIETET"CIEITTTTITTTCIETUITCTTTTTT"TT 10 20 30 40 50 60 70 80 90 100 110 120 130140150 160 170 180190200210 r-p T’T i Trr i । i i i i । f 6.80 7.00 7.20 7.40

26680.D NP112701.M Fri Dec 07 13:11:42 2001 Page 9

NYC-WTC_000032073

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