GCMS comments for sample AD26533 detecting 1,1,2,2-Tetrachloroethane

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Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0701\26533.D Vial: 7 Acq On 7 Dec 2001 11:35 pm Operator: GALOS Sample gc/ms unknown 11/6 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 Hydrogen azide Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

5.05 1.60 ng/uL 382921 1,4-Dichlorobenzene-d4 11.88

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Hydrogen azide 43 HN3 007782-79-8 4 2 Acetic acid, anhydride 102 C4H603 000108-24-7 4 3 Acetic acid, anhydride 102 C4H603 000108-24-7 2 4 Propane, 2-nitro- 89 C3H7NO2. 000079-46-9 1 'Abundance Scan 23 (5.051 min): 26533.D (-) m/z 43.00 100.00% 43

5000

4.90 5.00 5.10 5.20 5.30 5.40 5.50 36 401 60 84 10111—0011—0000——gETTtTtT 11′0111111111111101111—01700" I’ m/z .42.05 42.05 (6.40% m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33: Hydrogen azide 43

5000 - 15 1WWNIWTIWTTTTIT 1 ■ i ■ ■ 4.90 5.00 5.10 5.20 5.30 5.40 5.50 29 m/ Z .44.00 3.16% ■ l ■ ■' ■ I ■ • ... I.. ' I < ” *)1'11111" 11 l . i ■ ’ ■ • i TIT i''1 ■ i' ■ ■ ■ r " ‘ i V m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #1580. Acetic acd. anhyaride 43 i'11' 111 ■ • i'' ■ ■ i 111111 4.90 5.00 5.10 5.20 5.30 5.40 5.50 5000 m/z 45.00 1.83%

m/z--> Abundance 29 60 ■ i' ■" r ' " i ■ •" r u ■ i ‘' i " " i" " i• •• 'r'" f'"i ' i "" i<' "i ‘ r ■" i'" ■ i• ■" i" '' i' 5_ 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 #63470: Acetic acid, anhydride 43 87

AL 4.90 5.00 5.10 5.20 5.30 5.40 5.50 m/z 41.00 1.32%

W. 5000

15 29 60 87 TTTTTTTTTTTTTTTT r "11 — +T TTTTTtT ■ r " ■ i' i" " i r"■i m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4.90 5.00 5.10 5.20 5.30 5.40 5.50

26533.D NP112701.M Thu Dec 13 11:23:39 2001 Page 1

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