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GCMS analysis results for sample AD26682, Dec 10 2001

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Laboratory report documenting GCMS analysis of sample AD26682 identifying unknown compounds on December 10, 2001.

NYC-WTC_000032093–000032113

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC0501\26682.D Vial: 2 Acq On 5 Dec 2001 9:41 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Hydrogen azide Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

4.99 2.09 ng/uL 720442 1,4-Dichlorobenzene-d4 11.86

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Hydrogen azide A 43 HN3 007782-79-8 4 2 Acetic acid ethenyl ester 86 C4H6O2 000108-05-4 2 3 Acetic acid,/anhydride 102 C4H6O3 000108-24-7 2 4 Acetic acid, anhydride 102 C4H603 000108-24-7 2 Abundance Scan 16 (4.991 min): 26682.D (-) m/z 43.00 100.00% 43

5000

TIT I ° 1 • P ■' ■ i • •' ' i 4.90 5.00 5.10 5.20 5.30 5.40 36 40, 57 60 87 limit! TTTTTT I I I I | ! . > . | > t . > J l ( l ! | ■ I +1 i'' TTTTTTTT m/z 42.05 5.66%

NN i111111 ' i1 I'1111 miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33: Hydrogen azide 4b I

5000 15 1 ' ' ' ' I 1 1 ’ ' J ' ' ' • I' • ' ' I 1 4.90 5.00 5.10 5.20 5.30 5.40 29 m/z 44.00 2.90% TTTTIETT i111 • I — ’ I TTTTTT I’ m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 I Abundance #62796 Acetic acid ethenyl ester 43 I 4.90 5.00 5.10 5.20 5.30 5.40 1.27%

M 5000- m/z 44.95

15 86 27 31 ।..>.11j..Inui 1 , i’11'r11 *i11" i■ "111••'T'•■■।1■••i•••■। " ■11• m/z--> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #1680: Acetic acid, anhydride

A 43 4.90 5.00 5.10 5.20 5.30 5.40 m/z 41.00 0.53% 5000-

29 60 87 ! ] PTTTT । m । । । । । । । . r > I । । T TH +t 1111' I'1" 1111 ‘ i'«>11" •11 - <। TT‘‘T I’ miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4.90 5.00 5.10 5.20 5.30 5.40

26682.D NP112701.M Fri Dec 07 13:13:12 2001 Page 1

NYC-WTC_000032101

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NYC-WTC_000032101Source: NYC Law Department, mirrored locally

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