GCMS comments for sample AD26710 detecting phthalate and tetrachloroethane

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Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0501\26710.D vial: 4 Acq On 5 Dec 2001 11:29 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 Hydrogen azide Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

5.05 4.58 ng/uL 1555670 1,4-Dichlorobenzene-d4 11.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Hydrogen azide 43 HN3 007782-79-8 4 2 Acetic acid, anhydride 102 C4H603 000108-24-7 2 3 Acetic .acid, anhydride 102 'C4H603 000108-24-7 2 4 Butane, 2,2,3,3 -tetranitro- 238 C4H6N4O8___020919-97-5 1 Abundance Scan 23 (5.052 min): 26710.D (-) m/z .43.00 100.00% 43

5000 J Ir' ■ ■ i ■•■ ■ iTT 4 90 5.00 5.10 5.20 5.30 5.40 5.50 36 401 51 56 60 84 87 ! 0+ ■ i' " ■ i ■ ■ ■ ■ r F’TTTTTTTTT +1 I " " I'11' I' i" • ■ । । 1" m/z ,42.00 6.11% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33: Hydrogen azide 43

15 7 5000 - 4.90 5.00 5.10 5.20 5.30 5.40 5.50 m/z .44.00 2.53% ! ■ i" " ।1 ■ U’"E11ETT-0"IEII"EEITETEII’T"’-CSIO’’III’I’’IT miz-> 5__ 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #63470; Acetic acid, anhydride 43 i ■ ■ ■ ■ i 4.90 5.00 5.10 5.20 5.30 5.40 5.50

UW 5000 m/z .41.00 1.14%

15 29 60 87 ’ 1 r ■'' i ‘■ r ' ■ ■ i i'''' i" ' ' 111" I ‘ 11'111'11111111111111 TT miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #1680: Acetic acid, anhydride 43 4.90 5.00 5.1 5.20 5.30 5.40 5.50 m/z 45.00 1.08% 5000-

miz-i Tp 5 p-m TUuTreiT 10 15 20 25 29 30 35 — 1111 ‘ ■ i"'' r " ' i" " r • • ■ r ■ " r " ■ r " ' r " ■ i'" ' i' 40 45 50 55 60 60 65 70 75 80 85 87 90 95 j i ■ • • • t ■ ■ ■ ■ i T’T 4.90 5.00 5.10 5.20 5.30 5.40 5.50 Tp-T

26710.D NP112701.M Fri Dec 07 13:14:00 2001 Page 1

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