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GCMS comments for sample AD26710 detecting phthalate and tetrachloroethane

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Analysis report dated December 31, 2001, identifying bis(2-Ethylhexyl)phthalate and 1,1,2,2-Tetrachloroethane in sample AD26710.

NYC-WTC_000032114–000032127

Folder label: “GCMS X 11/7/01 A 12/6/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\HPCHEM\l\DATA\DEC0501\26710.D Vial: 4 Acq On 5 Dec 2001 11:29 am Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 2-Butanol, 3-methyl-, (S)- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.19 11.98 ng/uL 4070870 1,4-Dichlorobenzene-d4 11.87

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l 2-Butanol, 3-meth (S) - 88 C5H120 001517-66-4 40 2 N-Ethylformamide 73 C3H7NO 000627-45-2 9 3 2-Butanol, 3-methyl- 88 C5H120 000598-75-4 9 4 2-Butanol, 3-methyl - 88 C5H120 000598-75-4 9 Abundance Scan 256 (7.188 min): 26710.D (-) m/z 45.05 100.00% iI 4 < 45

5000 61 73 • p ' ' ‘ I ‘ ' 6.80 7.00 7.20 7.40 7.60 — ’I’TT mm I'1 +.. 91.................. T’TTTTTT36 207 T" ” i ” " ।। r "111 m/ z 43.00 57.67% miz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance I #852: 2-Butanol, 3-methyl-, (S)- I 45

5000 ; I ' ' ' ‘ I ' ' ' ' I ' 1 • ' I ' 6.80 7.00 7.20 7.40 7.60

55 73 m/ z 73.05 37.83% 27 | I 1 87 I PT’IIETTTTTTTT m/z-> m I'Ml i •'" i" " r ■" i i" " i"" r 1" i" " i" " i 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #292: N-Ethylformaride 30 73 .......... 4— 6.80 7.00 7.20 7.40 7.60 5000 m/ Z 61.10 36.90% 44 58

15 L. r1" I’CTTNIUTTTT’T ' |11111'1'111' ’' I " " I ‘1'11 " ’ TTTTETT . । ।।. 111.11 m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 200210 Abundance #62961: 2-Butanol, 3-methyl- 45 6.80 7.00 7.20 7.40 7.60 m/ z 44.05 11.46% 5000

. 27,. 5. 7 Trp-rTTprrrpTTTp-mp^ 87 i" " r'" i11'11 “ " I TUIUIUUTTE"EU—OEg"Terr m/z-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 6.80 7.00 7.20 7.40 7.60

26710.D NP112701.M Fri Dec 07 13:14:02 2001 Page 2

NYC-WTC_000032122

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