GCMS calibration data for TCLP analysis dated December 7, 2001

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Data File C:\HPCHEM\1\DATA\DEC0 701\LB.D Vial: 2 Acq On 7 Dec 2001 7:01 pm Operator: GALOS Sample gc/ms unknown 11/6 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 12 Ether, 3-butenyl propyl Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

10.31 3.24 ng/uL 1005370 1,4-Dichlorobenzene-d4 11.88

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Ether, 3-butenyl 1propyl 114 C7H140 034061-75-1 23 2 Hexane, 2-methyl- 100 C7H16 000591-76-4 17 3 Oxirane, 2-.methyl-3-propyl-, cis- 100 C6H120 006124-90-9 17 4CH2=CHCH2C(O)OCH3_ * Abundance Scan 597 (10.314 min): LB.D (-) 100 C5H802 m/ z 003724-55-8 43.05 100.00% 14 43

5000

- TTt 39 1, 50 73 55 59 85

TurH 1]+-69+4 89 100 m/z A 10.00 10.20 10.40 10.60 59.10 35.60% ‘til

L miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #3059: Ether, 3-butenyl propyl 43

5000 1 • !• • ■ - ‘ 11143 1 11—T 10.00 10.20 10.40 10.60 55 73 85 m/z 55.10 33.08% 30 391 T 11....।> <1111.■।(i>i 11111111 * । * * * • i * * * mz—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #63434; Hexane. 2-methyl- 43 — —. TT ■ 1 10.00 10.20 10.40 10.60 5000 m/z 57.10 32.85% 57 85 29

IA 39 69 100 T1—m——0021—7T i tpmmT । —TT—TuT ।।. >.. ।. 111—00—001000111 miz->_ 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1531: Oxirane, 2-methyl-3-propyl-, cis- TTTTDT TTT 43 10.00 10.20 10.40 10.60 m/z 41. 31.34% 57 5000 71 85

miz—> . 11., <, ।, । > i j. •.. 11111 ■t-rn-p-n-rf 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 ■ I'1 • ■ i ■ ■ ■ • i rrp-rrrp-rr 100 Opnp—upu frTTTr U 10.00 10.20 10.40 10.60

LB.D NP112701.M Thu Dec 13 11:28:44 2001 Page 12

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