GCMS sample AE11154 analysis with surrogate recovery, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\020515\11154.D Vial: 20 Acq On : 16 May 2002 6:34 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 3 Quinoline, 3-bromo- Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T. 28.90 0.20 ug/1 20783 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Quiroline, 3-bromo- 207 C9H6BrN 005332-24-1 27 2 2-Ctloroaniline-5-sulfonic acid 207 C6H6C1NO3S 000098-36-2 27 3 Quiroline, 3-bromo- 207 C9H6BrN 005332-24-1 27 4 Oxirane, 2-(2-bromoethyl)-2-(t-b... 294 CllH23BrO2Si 119043-14-0 12 Abundance Scan 4395 (28.902 min): 11154.D (-4387) (-) m/z 207.00 100.00% 207

86 5000 172 49 244 102 136 28,60 28.80 29.00 29.20 36 I 75 > ■ ! । >■ ■ ■ ■ । 1 । I ' i 1 1 • ■ i ' 1m I 1 1 1 1 I ' U 1 1 H 4 m/ z 208.80 92.50% n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #126483: Quinoline, 3-bromo- 128 207

5000 101 1i 28,60 28.80 29.00 29.20 75 m/z 86.00 58.97% 50 64 90

m/z-> 20 . 27 38 || | । 11 ,l ,117 I ' 1 ..... . 1 11 1 1 1 1 ...... 1 40 60 80 100 120 141 155 140 160. 181 180 200 h—220 PPP 240 Abundance #84878: 2-Chloroaniline-5-sulfonic acid 207

5000 m/z 172.00 40.94%

43 55 90 1 57.69 1114126 145.......... । 1 r ' ' i 1 । ■ । | । । ■ ■ | ■ ‘ । । । > । । । < i । i । । । i—i-1 । । । । । । । m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84880: Quinoline, 3-bromo- ■ ■ i ■ • • ■ i > ‘ IIII’IITIII 128 207 28.60 28.80 29.00 29.20 m/ z 48.90 33.63%

5000 101 75 50 AA

m/z—> -27.38.4.6 20 40 60 80 90 1.^117 ||| 141152 - 100 120 140 160 181 180 200 220 240 28.60 28.80 29.00 29.20

11154.D SCAN020507.M Thu May 16 14:37:46 2002 Page 5

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