GC/MS analysis results for sample AE11416, May 28 2002

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Data File : C:\MSDCHEM\1\DATA\051702\11415.D Vial: 24 Acq On : 18 May 2002 8:21 am Operator: Mclean Sample : 5/15 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 4 Phenanthrene, 9-methyl- Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T. 22.58 0.26 ug/L 253598 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53 2 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 3 4 Bitoscanate 2,4-Diamino-6-(hydroxymethyl)pte... Abundance Scan 3319 (22.580 min): 11415.D (-3308) (-) 192 192 C8H4N2S2 C7H8N60 192 004044-65-9 000945-24-4 /4 0 m/z 192.10 100. Q0% 3o 5000

96 146 160 08 70 82 । 22.20 22.40 22.60 22.80 23.00

m/z-> 40 0 ' i " ■1111 " 111 " i" '' i TTTTH I 118 I l" I I I I I I I I I I I ! I I I I I'

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 r | ' i i+ i ’ ' । | । । ' i | i i r ■ | L m/z 191.10 20.35% Abundance #81033: Phenanthrene, 9-methyl- 192

5000 ' I 1 ‘ 1 ‘ 1 1 1 22.20 22.40 22.60 22.80 23.00 m/z 146.10 16.22% 96 165 . . 29 39 51 63 74 83 J 115 126 139 152 j 176 . 0 ' I “ '11 ' n ' 11 1' 1 I'1111 ''H ' l1 ITi P ' rl l 11 • 1111»I • Cl 1111«111JI I'j 11111'»»11 ] I'n I [ 11-] | | | I "i" mz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80953: 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 ----- 161 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.10 14.18% 77 91 121 149 177

m/z-> 0*i 1111 < । > । 52Lji 64 ... ..... I i, ’ I’’’’ ।11'' ।'11111"1111 ■11IT 103 • l — 138 1 1 r | > l1, i , , । lh , , । , r| , i i q 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 4 - Abundance #125828: Bitoscanate 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 12.22%

5000

134 90 160 50 63 75 ,102 122 148 176 0 +++ , IT, । I > । । I I , |‘I , । > 14111, 1111 plaponsi) 1 T' 1 ' 1 1 1 1 1 ‘ I ' 1 ‘ 1 I ' miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

11415.D 050102.M Tue May 21 15:57:53 2002 Page 6

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