GCMS analysis results for sample AE11309, May 28, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \HPCHEM\ 1 \DATA\MAY2 102\11308.D Vial: 22 Acq On : 21 May 2002 9:28 pm Operator: Sample : EXTRACTS/14 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C : \DATABASE\NBS7 5K. L

Peak Number 2 3-Pyrrolidinol Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 9.91 0.53 ug/1 32651 1,4-Dichlorobenzene-d4 12.14 Hit# of Tentative ID MW MolForm CAS# Qual

1 3-Pyrrolidinol 87 C4H9NO 040499-83-0 9 2 Acetone 58 C3H60 000067-64-1 9 3 2-Hexanone, 5-methyl- 114 C7H140 000110-12-3 9 4 Acetic acid, 1-methylpropyl ester 116 C6H1202 000105-46-4 9 Abundance Scan 532 (9.914 min): 11308.D (-) m/z 43.05 100.00% 43

5000 58 87 1 ' ' I ' '

' 1 ..... m/z->____ 20 30 1’40 -4 50 —— .. 60 198 ... 1 । 1 1 1 1 । 1 1 1 1 । 1 1 1 1 i ' 1 1 1 i 1 1 1 1 i 1 70 80 90 100 110 120 m/z 9.60 9.80 58.10 10.00 10.20 22.60% Abundance #752: 3-Pyrrolidinol 43

5000 1 ' । 1 1 ' 1 । 1 ■ 1 1 । 1 1 1 1 i 9.60 9.80 10.00 10.20 57 68 87 m/ z 87.05 17.68%I

miz-> 20 30 40 L 50 60 , , |l .... ।....... fl 70 80 90 100 110 120 Abundance #62322: Acetone 43

9.60 9.80 10.00 10.20 5000 m/ z 41.15 13.43%I

m/z-> Abundance

5000 27 .....Il,,, , , . t. ■ 1 i ■ ‘ 1 1 i 1 1 ' ' i 1 20 30 40 43 1 I ' r 50 58

60 i ' ' ' ' i ‘ 70 #64143: 2-Hexanone, 5-methyl- ' ■ i ' ' ■ ' i 1 1 ' ' i ‘ 80 90 100 ' 1 1 1 1 1 1 1 1 110 120 oo M 1 ' ' I 1 1 1 1 1 ' ' 1 ' 1 1 1 ' 1 1 1 ' 1 1 I

m/z 9.60 9.80 59.00 10.00 10.20 11.19%

58 27

m/z—> ... Il, — i 1 - ■ 71 I ■ i ■ ■ ■ ■ । ■ 85 ■ ■ ■ । ' • 99 - ■■ । । । । । । 114 । 1 । । । । IJ 20 30 40 50 60 70 80 90 100 110 120 9.60 9.80 10.00 10.20

11308.D GCMS0520.M Wed May 22 09:21:17 2002 Page 2

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