GCMS instrument log for sample AE10063, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\l\DATA\MAY2002\10063.D Vial: 14 Acq On : 20 May 2002 7:57 pm Operator: Sample : EXTRACTED 5/9 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 3-Pyrrolidinol Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 9.92 0.73 ug/1 41583 1,4-Dichlorobenzene-d4 12.14

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Pyrrolidinol 87 C4H9NO 040499-83-0 12 2 4-Pentin-2-one, 4-methyl- 98 C6H10O 003744-02-3 9 3 Acetone 58 C3H60 000067-64-1 9 4 Acetic acid, 1-methylpropyl ester 116 C6H12O2 000105-46-4 9 Abundance 7 Scan 533 (9.922 min): 10063.D (-) m/z 43.05 100.00%| • 43

5000

58 7—1 l__ — [ I 87 । 98 9.60 9.80 10.00 10.20 m/z—> 15 20 25 30 35 391 + +51+ 40 45 50 60 65 55 69 H 111111 70 75 80 85 90 95 100 105 ।111' ।11' ‘ । 11' । ■r ।11 m/z 58.00 19.32%| Abundance #752:3-Pyrrolidinol 43

5000 ' ■ i ■ ■ ' 1 i 9.60 9.80 10.00 10.20 57 87 m/ z 87.05 15.80%| 68 " i ‘" i ■ ‘" ij "11" " i TTTTTWTTPTTTTT ' i' " ' r " ‘ i" " i ■" m/z—> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1244:4-Penten-2-one, 4-methyl- 43 ■ ' I ' ' ' ' I ' ' ' ' I ' ‘ ‘ ' 1 ' ' I 9.60 9,80 10.00 10.20 5000 m/z 41.15 13.00%! 83 29 55 98 -3, —mmmmmmP qp m/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance 43 #62326: Acetone W/MNA, YA ■ 1i 1 11 ' i r ' ' ITTT 11 9.60 9.80 10.00 10.20 m/ z 59.10 11.96%| A 5000 58 V m/z—> | ?7 36 I I I 1 i I | 1 . rl | 11 > I | I I I 1 । ! 1 1 1 | | 1 1 I | 1 1 I t | I I ! I | I I I f I 1 1 1 1 | I I f I | I 1 1 1 | | | 1 1 | 1 1 1 | | 1 1 | ! | 1 1 ! 1 | r r

15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 9.60 9.80 10.00 10.20

10063.D GCMS0520.M Tue May 21 11:37:43 2002 Page 2

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