GCMS analysis results for sample AE10891, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \HPCHEM\1\DATA\MAY1502\10891.D Vial: 9 Acq On : 15 May 2002 9:54 pm Operator: Sample : GC/MS SCAN 5/10 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0510.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 4 3-Pyrrolidinol Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

9.94 0.72 ug/1 44616 1,4-Dichlorobenzene-d4 12.16 Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 3-P'yrrolidinol 87 C4H9NO 040499-83-0 17 2 B anoic acid, 3-oxo-, methyl ester 116 C5H803 000105-45-3 12 3 4 -Methyl-2-pentyl acetate 144 C8H16O2 000108-84-9 10 44-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-3 9 undance Scan 534 (9,937 min): 10891 .D (-) m/ z 43.05 100.00% 43

5000

58 83 1 ■ i ' ■ ■ ‘ । ■ i 1 > ■ । । 1 1 1 1 । । 98 9.60 9.80 10.00 10.20

m/z-> .......................... ■ । 1 1 1 1 । 1 1 1 > । ■ 20 30 । I 40 +4*4 50 60 69..... Ill, 2..) । ■ 1 ' 1 i ■ 1 ' 1 i ' 1 1 ■ i 1 70 80 90 100 110 120 m/ z 58.00 20.02% Abundance #752:3-Pyrrolidinol ... 43

5000 ' ' i ' ' ■ 1 i ' 1 9,60 9.80 10.00 10.20 57 87 m/Z 82 . 95 18.04% 68 " l ■ ''■•■■I ' mfz-> 20 30 40______ 50 60 70 80 90 100 110 120 Abundance #64260: Butanoic acid, 3-oxo-, methyl ester 43 1 K* 9.60 9.80 10.00 10.20 5000 m/z 87.05 15.42%

31 59 69 74 85 101 116 ...... , J. .... I ....... I ■ i ■ ■ ■ ■ i ' ■' । • I ■ ■ । » t ■ • ■ ■ ।■■ ■ ■ . । • i ■ । ■ miz-> 20 30 40 50 60 70 80 90 100 110 120 Abundance #8382:4-Methyl-2-pentyl acetate 43 9.60 9.80 10.00 10.20 m/ z 59.10 9.85%

5000 69 87 j7............... | 56 61 — 102 - l ■ • ■ ■ । । । i TIITTTTTT rn-it ' । ' I ' 1 ' 1 1 ' 1 ' i ■ ' ' ‘ i 1 ' 1 ' i ' m/z—> 20 30 40 50 60 70 80 90 100 110 120 9.60 9.80 10.00 10.20

10891.D GCMS0510.M Fri May 17 10:17:33 2002 Page 4

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