GCMS analysis results for sample AE10893, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\l\DATA\MAY1502\10893.D Vial: 11 Acq On : 15 May 2002 11:51 pm Operator: Sample : GC/MS SCAN 5/10 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0510.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 3-Pyrrolidinol Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 9.94 0.63 ug/1 33273 1,4-Dichlorobenzene-d4 12.16 Hit# of Tentative ID MW MolForm CAS# Qual

1 3-Pyrrolidinol 87 C4H9NO 040499-83-0 23 2 3-Oxetanol, 2,2,3-trimethyl- 116 C6H1202 025910-96-7 23 3Acetic acid, 1-methylpropyl ester 116 C6H1202 000105-46-4 9 4 4-Penten-2-one, 4-methyl-________ 98 C6H10O 003744-02-3 7 Abundance Scan 535 (9,940 min): 10893. D (-) m/ z 43.00 100.00% 43

5000

58 87

m/z-> " r 1" i' m 1111111111111 'I'"1!' 49 ++ I TTPTTHTTTTTTTTTT 98

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 9.60 m/z 9.80 58.10 10.00 10.20 18.85% Abundance #752:3-Pyrrolidinol 43

5000 ■ ■ i ■ ' ' 1 i ' ■ 9.60 9.80 10.00 10.20 57 87 m/ z 87.05 15.60% 68

mfe-> ■' 11" ‘ r "11"111" " i ll ' i " " I ‘ ‘" i" " I'' 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 " J " i " ■' i" " r ■ ■ ■ i ■ "' i

Abundance #3281:3-Oxetanol, 2,2,3-trimethyl- 43 1 ■ । 1 1 > 1 । 1 1 1 I 11 ' ' 1 1 ' 1 1 I ' 9.60 9.80 10.00 10.20 5000 m/z 59.00 12.28% 58 71 27 86 ................ —H 111111111111 " ■ J 1" i " " I"111" " 111" I ........................ pp ' I " " I I miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #3301: Acetic acid, 1-methylpropyl ester 1 ' i 1 1 43 9.60 9.80 10.00 10.20 m/ z 41.10 8.60%

5000

56 87

m/z—> 29 opasspagg TT TH 61 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 73 | 101 9.60 9.80 AMN/ 10.00 10.20

10893.D GCMS0510.M Fri May 17 10:30:39 2002 Page 2

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