GCMS chain of custody form, sample AE10239, May 2002

NYC 9/11 Public Portal Document

'Data File : C:\MSDCHEM\1\DATA\020509\10239.D Vial: 17 Acq On : 10 May 2002 2:26 am Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020507.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C: \DATABASE\nist98.1

Peak Number 2 Thiocyanic acid, 2-benzothi... Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

31.09 0.32 ug/1 44323 Phenanthrene-dl0 31.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Thiocyanic acid, 2-benzothiazoly. . . 192 C8H4N2S2 006011-99-0 50 2 5H-Dibenzo [a, d] cycloheptene 192 C15H12 000256-81-5 42 3 2 - Propenal , 3 -(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42 4 2,4-Diamino-6- (hydroxymethyl) pte .. . 192 C7H8N6O 000945-24-4 40 Abundance / Scan 4768 (31.094 min): 10239.D (-4758) (-) m/z 192.10 100.00% 1912

5000

96 146 30.80 31.00 31.20 31.40 51 66,74 82 118 160 TT palk ’ m 111111111 / ; pl 111/11111'| > ■,.......................................................................... h j__ TTT - TTIT m/ z 96.20 22.09% m/z—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 192

5000 30.80 31.00 31.20 31.40 69 ano 13A m/z 191.20 16.45% . 45.. 1 1" '' 111'' I''111' 82 90 | 122 | " ' 1 I " ' 1 I I rr l, I !| I ■■ I 11 ■ I I | 1 1 I 1 | I I I I | U* ' F' 1 148 160 I | > I I I | I >•! I J I ! I I j 1 I 1 ■ | l.. J mlz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80999:5H-Dibenzo[a,d]cycloheptene 192 ----P4 30.80 31.00 31.20 31.40 177 5000 m/z 193.20 12.24% 89 165

m/z—> 30 39 51 63 76 97 115 128 139 152 I ‘ " ''l " " I'" " I ’ ‘ I ‘ h I 1 1 ri 'l' I 1 1 m ri 1-1 | । । ll | 1 | | i'| i i i i |Ti ■ i | ’ ’ । i I1 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 | 4ll " i"

Abundance #80953:2-Propenal, 3-(3,4-dimethoxyphenyl)- 19/2 30,80 31.00 31.20 31.40 161 m/ Z 82.10 9.98%

5000

77 149 177

/z—> -mP 52 64 4+ 91 103 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 121 - 138 | ’ 1’1 1 1 i 1 1 1 i ■ 1 30.80 31.00 31.20 31.40

10239.D SCAN020507.M Tue May 14 14:25:05 2002 Page 4

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