GC/MS results for unknown compounds and surrogates, sample AE10981, May

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\051402\10981.D Vial: 10 Acq On : 14 May 2002 8:50 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 7 Isobenzofuran-1,3-dione, 4,. Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 31.01 0.43 ug/L 475200 Chrysene-dl2 30.81 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Isobenzofuran-1, 3-dione, 4,5-dim... 208 C10H8O5 001567-56-2 9 2 6-Amino-2-(m-tolyl)-1,3,5-thiadi... 235 C10H9N3S2 094014-50-35 3 3-Chlorothiophene 118 C4H3C1S 017249-80-8 5 4 1-Bromopropadiene-1,2 118 C3H3Br 1000222-14-2 4 Abundance Scan 4754 (31.012 min): 10981.0 (-4753) (-) m/z 44.10 100.00% 44 106 118 208 239 Ah/wapteMMw 5000

30.60 30.80 31.00 31.20 31.40 0- ' ’ i 1 1 ' ' i । 1 । । -1 ■ ■ 1 ■ । ■ ■ ■ ■ i 1 1 1 1 i 1 1 ■ ■ । ‘ ‘ | ■ ■ ■ ■ | r m/z 106.00 97.57% m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84979: Isobenzofuran-1,3-dione, 4,5-dimethoxy- 44 78 208

104 135 5000 1BT 1 '"1 1 1 1 1 1 1 1 65 163 179 30.60 30.80 31.00 31.20 31.40 122 m/z 118.00 150 75.00% 93

miz-> 0- ) —la1 1udqu4l l ,44l th 4 + 20 40 60 80 100 120 140 160 180 200 TT 190 —77, IT 220 240 Abundance #53046: 6-Amino-2-(m-tolyl)-1,3,5-thiadiazine-4-thione 118 IT 1 ' i ■ ' r ■ i ■ ■ 235 30.60 30,80 31.00 31.20 31.40 5000 m/z 116.10 73.26% 91 43 65 143

n/z-> 01 -4l,u77l, 20 40 60 80 104 177 202 I , ’IIIIII- - '1 ’ ’’[1-II 100 120 140 160 180 200 Alal,— 220 240 Abundance #52766:3-Chlorothiophene 1 8 30.60 30.80 31.00 31.20 31.40 m/z 207.95 62.15% 83 5000 45

58

n/z-> 0 12 ■ ■ ■ i ■ 20 32| 40 1,681801-44 60 100 120 TTT 140 160 180 200 220 240 30.60 30.80 31.00 31.20 31.40

10981.D 050102.M Thu May 16 14:37:16 2002 Page 10

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