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GC/MS results for unknown compounds and surrogates, sample AE10981, May

Machine-extracted title · confidence 100%

Laboratory report showing GC/MS analysis of sample AE10981 with surrogate recovery data for 2,4-DDD.

NYC-WTC_000023970–000023990

Folder label: “GCMS X 5/10/02 A 5/14/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\051402\10981.D Vial: 10 Acq On : 14 May 2002 8:50 pm Operator: Mclean Sample : 5/10 kb Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 Isobenzofuran-1,3-dione, 4,. Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 31.01 0.43 ug/L 475200 Chrysene-dl2 30.81 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Isobenzofuran-1,3-dione, 4,5-dim... 208 C10H8O5 001567-56-2 9 2 6-Amino-2-(m-tolyl)-1,3,5-thiadi... 235 C10H9N3S2 094014-50-3 5 3 3-Chlorothiophene 118 C4H3C1S 017249-80-8 5 4 1-Bromopropadiene -1,2 118 C3H3Br 1000222-14-2 4 Abundance Scan 4754 (31.012 min): 10981.D (-4753) (-) m/z 44.10 100.00%! 44 106 118 208 239 5000

30.60 30.80 31.00 31.20 31.40 0- 1' i1 1 111 . . i ■ . . ■ i . . m/ z 106.00 97.57% rn/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84979: Isobenzofuran-1,3-dione, 4,5-dimethoxy- 44 78 208 104 135 । — ।।11111 5000 TI.T 65 163 vs 30.60 30.80 31.00 31.20 31.40 122 m/z 118.00 75.00% 0- ■ ■ i ■ ■ . AL 4 u t— H TI 190 M., 200 220 240 ..180 ■ . i . . . ■ i . ' 20 40 60 80 100 120 140 160 Abundance #53046: 6-Amino-2-(m-tolyl)-1,3,5-thiadiazine-4-thione 1 8

235 30.60 30.80 31.00 31.20 31.40 5000 m/z 116.10 73.26%l 91 43 65 143

niz- > 0- ' ■ i ■ 20 40 60 177/194.... 80 100 120 I 140 160 177 180 200 202 29 — 220 240 Abundance #52766: 3-Chlorothiophene i 1 ■ ■ 1 i 1 ■ ■ ' i ' ' ‘ ' i ' ' 1 8 30.60 30.80 31.00 31.20 31.40 m/z 207.95 62.15%| 83 5000 45

58 _ 0 12 r-n-j-r 321 M,i IIui 69i1 r........................ .... ■ ■ i ■ ...................... ... । । । । TTT TTTTTurtmr n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 30.60 30.80 31.00 31.20 31.40

10981.D 050102.M Thu May 16 14:37:16 2002 Page 10

NYC-WTC_000023984

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NYC-WTC_000023984Source: NYC Law Department, mirrored locally

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