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GCMS analysis results for sample AE10137, May 2002

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Laboratory report showing GC/MS analysis results for sample AE10137 including surrogate recovery data on May 14, 2002.

NYC-WTC_000023439–000023453

Folder label: “GCMS X 5/9/02 A 5/13/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\051302\10137.D Vial: 9 Acq On : 13 May 2002 6:00 pm Operator: Mclean Sample : 5/9 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 6 Anthracene-diO- Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 23.11 0.45 ug/L 500793 Phenanthranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-d10- 188 C14D10 001719-06-8 87 2 Phenanthrene-diO 188 C14D10 001517-22-2 78 3 Naphthalene, 1,7-dimethoxy- 188 C12H1202 005309-18-2 36 4 Pentacyclo[7.3.1.1.(4,12).0(2,7)... 188 C14H20 1000215-61-8 36 Abundance Scan 3409 (23.109 min): 10137.D (-3404) (-) m/z 188.10 100.00% 188

5000

43 54 66 80 y 0 ' I " " I" ‘' r ' " 111"' i' । " r 11' 11 ■ ।111 " 1111" i11 " r 1 " i I132 I I I J I I I I I I I I I I160 T I > I I I I I — 22.80 23.00 23.20 23.40 m/z 189.10 14.70% m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79826: Anthracene-d10- its

5000 1 ' I1 ' I 1 1 1 1 I 1 1 1 ' I 22.80 23.00 23.20 23.40 m/z 94.05 13.13% 66 80 94 160 17 30 42 52 , , 1 108118 132 146 II, 170179 0 TIWTTTTTTTTTTTTTHT 11 rl I j । 11 11 I n 11 11 j 1111 i j । n 11 [ । । 11 [ I n 11 n'li 11 i ’ ’ 11 111 j i i | I’l’l’" i ! 11 mlz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #79827: Phenanthrene-d10 1tS

22.80 23.00 23.20 23.40 5000 m/z 184.05 11.53%

80 94 160 42 52 66 0- 30 1' “ 111 ■ i' ■■' i H.. 11 1TTT ।' i ■. i'1!''' q 108 118 132 146 , |, 179179 .1 mlz-> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 Abundance #79804: Naphthalene, 1,7-dimethoxy- ....................... ............... .............. 173 1tS 22.80 23.00 23.20 23.40 m/z 80.10 10.61% 5000 102 115 145 51 63 75 130 158 0- HH HHH 4 l. I'1" m/z—> 10 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 22.80 23.00 23.20 23.40

10137.D 050102.M Tue May 14 11:40:05 2002 Page 9

NYC-WTC_000023451

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NYC-WTC_000023451Source: NYC Law Department, mirrored locally

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