GCMS analysis results for sample AE10137, May 2002

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Data File : C:\MSDCHEM\1\DATA\051302\10137.D Vial: 9 Acq On : 13 May 2002 6:00 pm Operator: Mclean Sample : 5/9 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 7 Minoxidil Concentration Rank 4

R.T. EstConc. Area Relative to ISTD R.T.

34.89 0.31 ug/L 184601 Perylene-dl2 34.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Minoxidil 209 C9H15N50 038304-91-5 5/ 2 Cycloprop[a]indene, 6-bromo-1,la... 208 C10H9Br 055780-41-1 4 3 1-Pentanethiol, 2-methyl- 118 C6H14S 001633-89-2 4 4 2-Chloro-4-aminopyrimidine 129 C4H4C1N3 007461-50-9 4 Abundance Scan 5414 (34.890 min): 10137.D (-5413) (-) m/z 129.00 100.00% 119

84 115 191 209 5000 281 264 44 ■ 1 i ■ 34.60 34.80 35.00 35.20 0- ■ ■ i ■1 1 ' i 1 ' i ' 1 ■ ' i ........... PPP ,1140 1 ' I 1 1 ' 1 I ' 1 ' 1 1 1 m/ Z 83.90 52.49% m/z-> 20 40 60 80 100 120 160 180 200 220 240 260 280 Abundance #85245: Minoxidil 209 84

5000 192 34.60 34.80 35.00 35.20 431 67 109 164 "z 208.90 51.38%

0- - , a 44, 4 T 124137150 . i178 n11 1 i ' 1 ' i ■ ■ ■ ' i1 ' • ■ i ■ ' ■ 1 i ■'

miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #58424: Cycloprop[alindene, 6-bromo-1,1a,6,6a-tetrahydro- 129 34.60 34.80 35.00 35.20 5000 m/z 115.10 50.28%

51 64 102115 m/z-> 01 14,27414. — *— 143 ——————193 164 u—utO 298 ’u’10——-IOO’ITr rtt10 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #4307:1-Pentanethiol, 2-methyl- .......... 1 1 । 1 ■ 43 34.60 34.80 35.00 35.20 m/z 118.05 48.34%

5000 27 56 71 84 118

0 I .97 J. ................................. /z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 34.60 34.80 35.00 35.20

10137.D 050102.M Tue May 14 11:40:05 2002 Page 10

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