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GCMS analysis results for sample AE10137, May 2002

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Laboratory report showing GC/MS analysis results for sample AE10137 including surrogate recovery data on May 14, 2002.

NYC-WTC_000023439–000023453

Folder label: “GCMS X 5/9/02 A 5/13/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C: \MSDCHEM\1\DATA\051302\10137.D Vial: 9 Acq On : 13 May 2002 6:00 pm Operator: Mclean Sample : 5/9 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 1,5-Naphthalenedithiole Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.26 ug/L 294081 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 45 2 Anthracene, 9-methyl- 192 C15H12 000779-02-2 42 3 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 42 4 Phenanthrene, 3-methyl- 192 C15H12 000832-71-3 42 Abundance Scan 3319 (22.580 min): 10137. D (-3309) (-) m/z 192.10 100.00%i 192

5000 - 96 146 160 40 49 64 82 22.20 22.40 22.60 22.80 23.00 —mpmtHm mmPH -H Ipr 118 0 m/z 191.10 18.29% mfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80950:1,5-Naphthalenedithiole 192

5000 159 22.20 22.40 22.60 22.80 23.00 115 128 m/z 193.10 13.85%| 69 79 147

mfe-> 0 ---+hi" drgl’rr++44 ,106 1——— hi Al 1'1 40 57 177 TTTBgour 20 30 40 50 60 70 80 90 100 110 .120 130 140 150 160 170 180 190 200 1 Abundance #125848: Anthracene, 9-methyl- 192

22.20 22.40 22.60 22.80 23.00 5000 m/z 146.10 13.73%|

27 39 51 63 82 96 J 115 126 -13g 152 EE 0 176 M 0 'T' rn'l'1 '-''I I U 11'111 ■ p'l.. P n , fl', n-, rll i~p 111 pT,, P ,, I P .. ,'p .., ri,, I, i’1’1 , J, Il, 1,, t’l ‘tTTTTT miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125842: Phenanthrene, 2-methyl- ..............A. 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 12.37%| 5000

96 27 39 8251,|| 115 | I126 63 139I I I I152 195 176 . 0 TI————0muNmmrr- tp rp I M | I I I | ■ n ]•! I > > | l'!1! I | I I'l l | I , 1’l 11—- 1 i ' ■ ■ ' i ■ ■ ■ ■ i ■ 1 • ' i ■ m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10137.D 050102.M Tue May 14 11:40:04 2002 Page 8

NYC-WTC_000023450

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NYC-WTC_000023450Source: NYC Law Department, mirrored locally

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