GCMS scan report for Method 508, April 2002

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Data File : C:\MSDCHEM\l\DATA\020419\08430.D Vial: 17 Acq On : 19 Apr 2002 11:53 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library- : C:\DATABASE\nist98.1 Peak Number 1 3-Buten-2-ol, 2-methyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.01 0.89 ug/1 1241360 1,4-Dichlorobenzene-d4 11.38 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 72 2 3-Buten-2-ol, 2-methyl- 86 C5H10O 000115-18-4 72 3 Butenol, methyl- 86 C5H10O 060766-00-9 72 4 Furan, tetrahydro-2-(methoxymeth... 116 C6H12O2 019354-27-9 50 Abundance Scan 328 (5.006 min): 08430. D (-322) (-) m/z 71.10 100.00% 43 71

5000 55 59 39 1 I ' ' 1 1 1 0 r TIuUf—um

n/z-> 01 5 -++ +++ 1,411+711,67 I . 50 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 । 8487 I J > ' f-r''' |' I f i H 11'' | ■ 111 4.60 4.80 5.00 5.20 5.40 m/z 43.10 89.51% Abundance #114555:3-Buten-2-ol, 2-methyl- 43 71 5000 PrT!*x9*1mun—mmTTRP 59 4.60 4.80 5.00 5.20 5.40 27 31 39 m/z 41.05 65.88% 1518 53

miz-> ol " i ■" ■!' ■■ ■! ■ ■!' i ■■' ■ 11 HI i li ■ 5 10 15 +F9LF9——67 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 thmpmhmm 86

Abundance #114556:3-Buten-2-ol, 2-methyl- 71 43 1 1 I 1 1 1 ' I 1 1 4.60 4.80 5.00 5.20 5.40 5000 m/z 69.10 52.83% 59 27 31 39 .53

miz-> +594661.63.67+ ,74 01 "I"'......... ■ ■ 11 " ■'! । 11! '' ■ I'' ll I ll ।111 86 i" 11111111111" 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 "" 11

Abundance #24435: Butenol, methyl- 4111 43 71 4.60 4.80 5.00 5.20 5.40 m/z 59.10 35.43% 5000 59 27 15 31 39 53

n/z-> 0 5-121.18,241 14..36.41/,46.59,1,561+.63,67474.79,838 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 m aPM f I I I I 4.60 4.80 5.00 5.20 5.40

08430.D SCAN020418.M Mon Apr 29 08:29:45 2002 Page 16

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