GCMS analysis results, sample AE09155, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\050902\9155 .D Vial: 20 Acq On : 10 May 2002 7:36 am Operator: Mclean Sample : 5/8 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 10 4-Bromo-3-chloroaniline Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

34.94 0.62 ug/L 317660 Perylene-dl2 34.70

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Bromo-3-chloroaniline 205 C6H5BrClN 021402-26-6 7/ 2 Benzenamine, 4-bromo-2-chloro- 205 C6H5BrClN 038762-41-3 7 3 Vanadium, (.eta.7-cycloheptatrie... 207 C12H12V 012636-68-95 4 Anthranilic acid, N-methyl-, but... 207 C12H17NO2 015236-34/7 5 Abundance Scan 5422 (34.937 min): 9155.D (-5421) (-) m/z 207.00 100.00% 129 207

86 116 191 pkutn"ypHp""" 5000 44 264 73 281 34.60 34.80 35.00 35.20 OTH I I , I, , m/z 129.50 95.67% nz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #84857:4-Bromo-3-chloroaniline 207

................................... 5000 34.60 34.80 35.00 35.20 63 90 126 m/z 116.20 54.80% 45 । 0- ml II । ill । •_ lit i ■1 ■11 ■ ■ ■ ■ ।11 *11 ■ r* ■ * • ! " * * । - I * niz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #84854: Benzenamine, 4-bromo-2-chloro- 207 ------ 34.60 34.80 35.00 35.20 90 5000 m/z 191.00 51.39% 63 126 44 .

n/z-> o—Hl—4?—+ 103 40 60 80 143 1 ' 1 1 I ‘ 100 120 140 160 180 200 220 240 260 179 ' 1 1 1 1 ' ' 1 1 "' ■ i ■ 1 1 ' i ■ 1 ' ' i ■ ■ ■ ■ i ‘ 1

280 I Abundance #126462: Vanadium, (.eta.7-cycloheptatrienylium)(.eta.5-2,... Til Til 207 34.60 34.80 35.00 35.20 m/z 132.80 50.77% 129 51 5000 116

76 90 . 142 81 m/z—> 39 01 ' "'I ' ' ' I 40 60 ( 4480 100 120 140 160 180 200 220 240 260 280 34.60 34.80 35.00 35.20

9155.D 050102.M Mon May 13 11:41:48 2002 Page 13

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