Volatile organic compounds results, Mar 13 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\O2MAR13\0313C10A.D Vial: 3 Acq On : 13 Mar 2002 10:21 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 14 11:13 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Mar 13 14:51:22 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.09 114 1515086 5.00 ug/L -0.09 24) CHLOROBENZENE-D5 21.74 117 1435027 5.00 ug/L -0.09 52) 1,4-DICHLOROBENZENE-D4 26.93 152 .754216 5.00 ug/L -0.07

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 630093 6.43 ug/L -0.09 Spiked Amount 5.000 Recovery = 128.60% 3) 4-BROMOFLUOROBENZENE 24.33 174 583410 4.76 ug/L -0.09 Spiked Amount 5.000 Recovery = 95.20% 25) TOLUENE-D8 18.44 98 1800557 5.20 ug/L -0.09 Spiked Amount 5.000 Recovery = 104.00%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 375095 9.00 ug/L 98 5) CHLOROMETHANE 5.49 50 460198 10.16 ug/L 97 6) VINYL CHLORIDE 5.59 62 329128 11.35 ug/L 94 7) BROMOMETHANE 6.58 94 352853 12.22 ug/L 94 8) CHLOROETHANE 6.72 64 320025 12.67 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.27 101 673664 12.12 ug/L 99 12) ACETONE 8.24 43 119116 15.37 ug/L 99 13) 1,1-DICHLOROETHENE 8.60 61 843028 12.78 ug/L 98 14) METHYLENE CHLORIDE 9.60 49 797478 10.25 ug/L 94 15) METHYL TERT BUTYL ETHER 9.91 73 910290 10.21 ug/L 96 16) TRANS-1,2-DICHLOROETHENE 10.27 61 880318 9.84 ug/L 96 17) 1,1-DICHLOROETHANE 11.15 63 1039543 9.41 ug/L 97 18) 2-BUTANONE (MEK) 11.99 43 139346 8.39 ug/L 88 19) 2,2-DICHLOROPROPANE 12.38 77 854599 10.49 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.46 96 636882 9.37 ug/L 98 21) CHLOROFORM 12.80 83 1162822 10.02 ug/L 98 22) BROMOCHLOROMETHANE 13.18 49 474414 8.30 ug/L 87 23) 1,2-DICHLOROETHANE 14.52 62 824776 11.25 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.69 97 889266 11.58 ug/L 99 27) 1,1-DICHLOROPROPENE 14.01 75 811359 10.79 ug/L 98 28) CARBON TETRACHLORIDE 14.28 117 772372 11.99 ug/L 98 29) BENZENE 14.61 78 2053831 9.65 ug/L 100 30) TRICHLOROETHENE 15.89 95 647494 10.34 ug/L 96 31) 1,2-DICHLOROPROPANE 16.24 63 535117 8.67 ug/L 98 32) DIBROMOMETHANE 16.92 174 322887 9.96 ug/L 98 33) BROMODICHLOROMETHANE 16.77 83 838961 10.82 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.25 63 189547 9.68 ug/L 93 35) METHYL ISO-BUTYL KETONE 17.33 58 94371 8.57 ug/L 94 36) CIS-1,3-DICHLOROPROPENE 17.86 75 820189 9.73 ug/L 99 37) TOLUENE 18.61 91 2225947 9.52 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.90 75 621273 10.31 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.27 97 372429 9.27 ug/L 97 40) TETRACHLOROETHENE 20.06 166 661475 9.85 ug/L 98 41) 1,3-DICHLOROPROPANE 19.80 76 693406 9.41 ug/L 98 42) DIBROMOCHLOROMETHANE 20.50 129 501906 10.41 ug/L 98 43) 1,2-DIBROMOETHANE 20.96 107 394516 9.64 ug/L 100 44) CHLOROBENZENE 21.83 112 1497775 9.34 ug/L 98 45) 1,1,1,2-TETRACHLOROETHANE 21.88 131 552358 10.39 ug/L 96 46) 2-HEXANONE 19.17 43 177569 6.34 ug/L 96 47) ETHYLBENZENE 21.88 91 2615111 9.85 ug/L 99 48) P & M-XYLENE 22.03 106 1819047 19.01 ug/L 92 (#) = qualifier out of range (m) = manual integration 0313C10A.D HP022702.M Thu Mar 14 11:14:00 2002 Page 1

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