Volatile organic compounds results, Mar 10 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02MAR10\0310C10.D Vial: 2 Acq On : 10 Mar 2002 12:12 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 10 12:50 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.09 114 1433372 5.00 ug/L -0.09 24) CHLOROBENZENE-D5 21.74 117 1372254 5.00 ug/L -0.09 52) 1,4-DICHLOROBENZENE-D4 26.92 152 696737 5.00 ug/L -0.09 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 538278 5.81 ug/L -0.09 Spiked Amount 5.000 Recovery = 116.20% 3) 4-BROMOFLUOROBENZENE 24.33 174 529556 4.56 ug/L -0.09 Spiked Amount 5.000 Recovery = 91.20% 25) TOLUENE-D8 18.44 98 1726631 5.22 ug/L -0.09 Spiked Amount 5.000 Recovery = 104.40% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 284011 7.34 ug/L 98 5) CHLOROMETHANE 5.47 50 384805 9.04 ug/L 98 6) VINYL CHLORIDE 5.59 62 295411 13.01 ug/L 95 7) BROMOMETHANE 6.58 94 314465 11.55 ug/L 94 8) CHLOROETHANE 6.71 64 338123 14.11 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.27 101 658855 12.53 ug/L 98 12) ACETONE 8.24 43 94555 12.89 ug/L 99 13) 1,1-DICHLOROETHENE 8.58 61 930804 14.91 ug/L 96 14) METHYLENE CHLORIDE 9.59 49 890896 12.11 ug/L 97 15) METHYL TERT BUTYL ETHER 9.89 73 871572 10.34 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.25 61 986000 11.65 ug/L 99 17) 1,1-DICHLOROETHANE 11.15 63 1137026 10.88 ug/L 97 18) 2-BUTANONE (MEK) 11.97 43 125797 8.01 ug/L 89 19) 2,2-DICHLOROPROPANE 12.36 77 915586 11.88 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.46 96 696951 10.84 ug/L 99 21) CHLOROFORM 12.79 83 1220898 11.12 ug/L 98 22) BROMOCHLOROMETHANE 13.16 49 470482 8.70 ug/L 97 23) 1,2-DICHLOROETHANE 14.51 62 716266 10.33 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.69 97 855291 11.65 ug/L 99 27) 1,1-DICHLOROPROPENE 14.01 75 828400 11.52 ug/L 98 28) CARBON TETRACHLORIDE 14.27 117 740350 12.02 ug/L 99 29) BENZENE 14.61 78 2018130 9.92 ug/L 98 30) TRICHLOROETHENE 15.89 95 628415 10.50 ug/L 98 31) 1,2-DICHLOROPROPANE 16.24 63 526181 8.91 ug/L 96 32) DIBROMOMETHANE 16.91 174 273532 8.83 ug/L 92 33) BROMODICHLOROMETHANE 16.75 83 753688 10.17 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 173641 9.27 ug/L 96 35) METHYL ISO-BUTYL KETONE 17.32 58 83830 7.96 ug/L 95 3 6) CIS-1,3-DICHLOROPROPENE 17.84 75 771912 9.58 ug/L 99 37) TOLUENE 18.61 91 2203205 9.85 ug/L 100 38) TRANS-1,3-DICHLOROPROPENE 18.88 75 558062 9.68 ug/L 100 39) 1,1,2-TRICHLOROETHANE 19.27 97 338309 8.80 ug/L 98 40) TETRACHLOROETHENE 20.06 166 642618 10.01 ug/L 97 41) 1,3-DICHLOROPROPANE 19.80 76 625570 8.88 ug/L 99 42) DIBROMOCHLOROMETHANE 20.50 129 438926 9.52 ug/L 100 43) 1,2-DIBROMOETHANE 20.94 107 347514 8.88 ug/L 98 44) CHLOROBENZENE 21.83 112 1438116 9.38 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.88 131 501676 9.87 ug/L 97 46) 2-HEXANONE 19.17 43 143999 5.37 ug/L 89 47) ETHYLBENZENE 21.86 91 2595316 10.22 ug/L 99 48) P & M-XYLENE 22.03 106 1765408 19.30 ug/L 93 (#) = qualifier out of range (m) = manual integration 0310C10.D HP022702.M Fri Mar 15 12:25:41 2002 Page 1

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