Volatile organic compounds blank results, Mar 8 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02MAR08\0308C10A.D Vial: 3 Acq On 8 Mar 2002 11:23 pm Operator: 201-wb Sample cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 10 13:03 2002 Quant Results File: HP022702.RES

Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.05 114 753992 5.00 ug/L -0.12 24) CHLOROBENZENE-D5 21.69 117 733610 5.00 ug/L -0.14 52) 1,4-DICHLOROBENZENE-D4 26.88 152 360419 5.00 ug/L -0.12

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.29 65 292004 5.99 ug/L -0.12 Spiked Amount 5.000 Recovery = 119.80% 3) 4-BROMOFLUOROBENZENE 24.28 174 269606 4.42 ug/L -0.14 Spiked Amount 5.000 Recovery = 88.40% 25) TOLUENE-D8 18.41 98 932394 5.27 ug/L -0.12 Spiked Amount 5.000 Recovery = 105.40%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.83 85 183974 8.88 ug/L 98 5) CHLOROMETHANE 5.45 50 267378 11.76 ug/L 96 6) VINYL CHLORIDE 5.57 62 212898 18.20 ug/L 98 7) BROMOMETHANE 6.54 94 202813 14.01 ug/L 91 8) CHLOROETHANE 6.69 64 ■ 211403 16.70 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.25 101 386420 13.97 ug/L 99 12) ACETONE 8.22 43 61023 15.82 ug/L 94 13) 1,1-DICHLOROETHENE 8.56 61 482389 14.69 ug/L 98 14) METHYLENE CHLORIDE 9.57 49 580341 15.00 ug/L 99 15) METHYL TERT BUTYL ETHER 9.88 73 545606 12.30 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.23 61 614639 13.81 ug/L 98 17) 1,1-DICHLOROETHANE 11.12 63 757295 13.77 ug/L 98 18) 2-BUTANONE (MEK) 11.95 43 70024 8.48 ug/L 90 19) 2,2-DICHLOROPROPANE 12.33 77 507745 12.53 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.43 96 474562 14.03 ug/L 95 21) CHLOROFORM 12.77 83. 837737 14.51 ug/L 100 22) BROMOCHLOROMETHANE 13.14 49 348693 12.25 ug/L 97 23) 1,2-DICHLOROETHANE 14.49 62 554336 15.19 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.66 97 608369 15.50 ug/L 98 27) 1,1-DICHLOROPROPENE 13.98 75 623887 16.23 ug/L 98 28) CARBON TETRACHLORIDE 14.23 117 511636 15.54 ug/L 97 29) BENZENE 14.57 78 1601319 14.72 ug/L 99 30) TRICHLOROETHENE 15.85 95 495420 15.48 ug/L 98 31) 1,2-DICHLOROPROPANE 16.21 63 439136 13.91 ug/L 98 32) DIBROMOMETHANE 16.87 174 204939 12.37 ug/L 89 33) BROMODICHLOROMETHANE 16.72 83 595379 15.03 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.21 63 136432 13.62 ug/L 98 35) METHYL ISO-BUTYL KETONE 17.28 58 60293 10.71 ug/L 91 36) CIS-1,3-DICHLOROPROPENE 17.81 75 596158 13.84 ug/L 99 37) TOLUENE 18.58 91 1795490 15.02 ug/L 99 3 8) TRANS-1,3-DICHLOROPROPENE 18.85 75 452779 14.69 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.24 97 282361 13.75 ug/L 97 40) TETRACHLOROETHENE 20.02 166 473522 13.79 ug/L 99 41) 1,3-DICHLOROPROPANE 19.77 76 512829 13.62 ug/L 100 42) DIBROMOCHLOROMETHANE 20.45 129 340654 13.82 ug/L 98 43) 1,2-DIBROMOETHANE 20.91 107 275308 13.16 ug/L 100 44) CHLOROBENZENE 21.78 112 1185301 14.46 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.83 131 396444 14.59 ug/L 99 46) 2-HEXANONE 19.14 43 108606 7.58 ug/L 92 47) ETHYLBENZENE 21.83 91 2144060 15.80 ug/L 99 48) P & M-XYLENE 21.98 106 1459073 29.83 ug/L 93 (#) = qualifier out of range (m) = manual integration 0308C10A.D HP022702.M Sun Mar 10 13:03:34 2002 Page 1

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