Volatile organic compounds results, Mar 6 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02mar06\0306C10A.D Vial: 17 Acq On 6 Mar 2002 8:58 pm Operator: 201-wb Sample cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 6 21:36 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Conc Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.07 114 785262 5.00 ug/L -0.10 24) CHLOROBENZENE-D5 21.72 117 773104 5.00 ug/L -0.10 52) 1,4-DICHLOROBENZENE-D4 26.90 152 362966 5.00 ug/L -0.10

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 297978 5.87 ug/L -0.09 Spiked Amount 5.000 Recovery = 117.40% 3) 4-BROMOFLUOROBENZENE 24.31 174 273868 4.31 ug/L -0.10 Spiked Amount 5.000 Recovery = 86.20% 25) TOLUENE-D8 18.42 98 996944 5.35 ug/L -0.10 Spiked Amount 5.000 Recovery = 107.00%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 273104 12.18 ug/L 97 5) CHLOROMETHANE 5.47 50 296026 12.46 ug/L 99 6) VINYL CHLORIDE 5.61 62 240829 19.86 ug/L 98 7) BROMOMETHANE 6.58 94 198621 13.21 ug/L 91 8) CHLOROETHANE 6.71 64 184243 14.04 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.27 101 344291 11.96 ug/L 99 12) ACETONE 8.24 43 51601 12.84 ug/L 96 13) 1,1-DICHLOROETHENE 8.60 61 544275 15.91 ug/L 97 14) METHYLENE CHLORIDE 9.59 49 596891 14.81 ug/L 96 15) METHYL TERT BUTYL ETHER 9.89 73 527831 11.43 ug/L 98 16) TRANS-1,2-DICHLOROETHENE 10.25 61 627967 13.55 ug/L 93 17) 1,1-DICHLOROETHANE 11.15 63 763171 13.33 ug/L 99 18) 2-BUTANONE (MEK) 11.99 43 68459 7.96 ug/L 96 19) 2,2-DICHLOROPROPANE 12.36 77 508079 12.03 ug/L 98 20) CIS-1,2-DICHLOROETHENE 12.46 96 436201 12.38 ug/L 98 21) CHLOROFORM 12.79 83 789875 13.13 ug/L 98 22) BROMOCHLOROMETHANE 13.16 49 351466 11.86 ug/L 90 23) 1,2-DICHLOROETHANE 14.51 62 519307 13.67 ug/L 99 26) 1,1,1-TRICHLOROETHANE 13.69 97 581719 14.07 ug/L 99 27) 1,1-DICHLOROPROPENE 14.01 75 610227 15.06 ug/L 98 28) CARBON TETRACHLORIDE 14.27 117 486479 14.02 ug/L 96 29) BENZENE 14.61 78 1583906 13.82 ug/L 98 30) TRICHLOROETHENE 15.89 95 474294 14.07 ug/L 97 31) 1,2-DICHLOROPROPANE 16.24 63 429987 12.93 ug/L 99 32) DIBROMOMETHANE 16.91 174 187652 10.75 ug/L 89 33) BROMODICHLOROMETHANE 16.75 83 553639 13.26 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 132171 12.52 ug/L 95 35) METHYL ISO-BUTYL KETONE 17.32 58 59900 10.10 ug/L 96 36) CIS-1,3-DICHLOROPROPENE 17.84 75 574019 12.64 ug/L 99 37) TOLUENE 18.61 91 1722283 13.67 ug/L 98 38) TRANS-1,3-DICHLOROPROPENE 18.88 75 430176 13.25 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.26 97 263971 12.19 ug/L 99 40) TETRACHLOROETHENE 20.04 166 435211 12.03 ug/L 94 41) 1,3-DICHLOROPROPANE 19.80 76 489630 12.34 ug/L 99 42) DIBROMOCHLOROMETHANE 20.48 129 299256 11.52 ug/L 97 43) 1,2-DIBROMOETHANE 20.94 107 254862 11.56 ug/L 98 44) CHLOROBENZENE 21.81 112 1109823 12.85 ug/L 96 45) 1,1,1,2-TETRACHLOROETHANE 21.86 131 357023 12.46 ug/L 99 46) 2-HEXANONE 19.15 43 101417 6.72 ug/L 94 47) ETHYLBENZENE 21.84 91 2000662 13.99 ug/L 99 48) P & M-XYLENE 22.01 106 1337334 25.95 ug/L 96 (#) = qualifier out of range (m) = manual integration 0306C10A.D HP022702.M Wed Mar 06 21:36:57 2002 Page 1

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