Volatile organic compounds blank results, Mar 8 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02mar11\0311R5A.D Vial: 3 Acq On : 11 Mar 2002 12:00 pm Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 11 12:39 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Mon Mar 11 11:11:58 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.03 114 1682577 5.00 ug/L -0.14 24) CHLOROBENZENE-D5 21.69 117 1625454 5.00 ug/L -0.14 52) 1,4-DICHLOROBENZENE-D4 26.87 152 846180 5.00 ug/L -0.14

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.27 65 652920 6.00 ug/L -0..14 Spiked Amount 5.000 Recovery = 120.00% 3) 4-BROMOFLUOROBENZENE 24.28 174 637554 4.68 ug/L -0.14 Spiked Amount 5.000 Recovery = 93.60% 25) TOLUENE-D8 18.39 98 2033850 5.19 ug/L -0.14 Spiked Amount 5.000 Recovery = 103.80%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.84 85 370860 8.09 ug/L 99 5) CHLOROMETHANE 5.46 50 325919 6.61 ug/L 98 6) VINYL CHLORIDE 5.56 62 246724 8.97 ug/L 95 7) BROMOMETHANE 6.55 94 193263 6.37 ug/L 95 8) CHLOROETHANE 6.68 64 191613 7.01 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.24 101 379988 6.16 ug/L 97 12) ACETONE 8.21 43 62805 7.30 ug/L 93 13) 1,1-DICHLOROETHENE 8.55 61 475915 6.49 ug/L 98 14) METHYLENE CHLORIDE 9.55 49 513769 5.95 ug/L 98 15) METHYL TERT BUTYL ETHER 9.86 73 462564 4.67 ug/L 98 16) TRANS-1,2-DICHLOROETHENE 10.22 61 501568 5.05 ug/L 98 17) 1,1-DICHLOROETHANE 11.10 63 599326 4.88 ug/L 98 18) 2-BUTANONE (MEK) 11.94 43 66255 3.59 ug/L 93 19) 2,2-DICHLOROPROPANE 12.33 77 461642 5.10 ug/L 100 20) CIS-1,2-DICHLOROETHENE 12.41 96 371429 4.92 ug/L 98 21) CHLOROFORM 12.75 83 647271 5.02 ug/L 98 22) BROMOCHLOROMETHANE 13.13 49 266478 4.20 ug/L 96 23) 1,2-DICHLOROETHANE 14.47 62 448387 5.51 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.64 97 482720 5.55 ug/L 98 27) 1,1-DICHLOROPROPENE 13.96 75 482400 5.66 ug/L 97 28) CARBON TETRACHLORIDE 14.23 117 413373 5.67 ug/L 98 29) BENZENE 14.57 78 1236886 5.13 ug/L 99 30) TRICHLOROETHENE 15.83 95 379060 5.35 ug/L 97 31) 1,2-DICHLOROPROPANE 16.19 63 320219 4.58 ug/L 97 32) DIBROMOMETHANE 16.87 174 166472 4.53 ug/L 98 33) BROMODICHLOROMETHANE 16.72 83 459431 5.23 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.20 63 101295 4.57 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.28 58 46048 3.69 ug/L 91 36) CIS-1,3-DICHLOROPROPENE 17.81 75 444287 4.65 ug/L 99 37) TOLUENE 18.56 91 1334011 5.04 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.85 75 345671 5.06 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.22 97 215566 4.74 ug/L 97 40) TETRACHLOROETHENE 20.01 166 371071 4.88 ug/L 97 41) 1,3-DICHLOROPROPANE 19.75 76 389045 4.66 ug/L 99 42) DIBROMOCHLOROMETHANE 20.45 129 262322 4.80 ug/L 99 43) 1,2-DIBROMOETHANE 20.89 107 213894 4.61 ug/L 96 44) CHLOROBENZENE 21.78 112 880581 4.85 ug/L 99 45) 1,1,1,2-TETRACHLOROETHANE 21.83 131 304474 5.06 ug/L 94 46) 2-HEXANONE 19.12 43 89521 2.82 ug/L 99 47) ETHYLBENZENE 21.81 91 1573310 5.23 ug/L 99 48) P & M-XYLENE 21.98 106 1078352 9.95 ug/L 93 (#) = qualifier out of range (m) = manual integration 0311R5A.D HP022702.M Mon Mar 11 12:41:22 2002 Page 1

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