Volatile organic compounds results, Mar 14 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02mar14\0314R5A.D Vial: 5 Acq On : 14 Mar 2002 12:00 pm Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 14 12:38 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Mar 13 14:51:22 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.10 114 2003237 5.00 ug/L -0.07 24) CHLOROBENZENE-D5 21.76 117 1899934 5.00 ug/L -0.07 52) 1,4-DICHLOROBENZENE-D4 26.94 152 1001137 5.00 ug/L -0.07 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.34 65 811739 6.27 ug/L -0.07 Spiked Amount 5.000 Recovery = 125.40% 3) 4-BROMOFLUOROBENZENE 24.35 174 782135 4.82 ug/L -0.07 Spiked Amount 5.000 Recovery = 96.40% 25) TOLUENE-D8 18.46 98 2368359 5.17 ug/L -0.07 Spiked Amount 5.000 Recovery = 103.40% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.88 85 213957 4.12 ug/L 98 5) CHLOROMETHANE 5.50 50 211717 3.67 ug/L 99 6) VINYL CHLORIDE 5.62 62 219922 5.74 ug/L 94 7) BROMOMETHANE 6.61 94 168220 4.84 ug/L 95 8) CHLOROETHANE 6.75 64 174161 5.44 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.30 101 337578 4.60 ug/L 98 12) ACETONE 8.28 43 83091 8.11 ug/L 99 13) 1,1-DICHLOROETHENE 8.62 61 502381 5.76 ug/L 95 14) METHYLENE CHLORIDE 9.62 49 506670 4.93 ug/L 95 15) METHYL TERT BUTYL ETHER 9.93 73 531974 4.51 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.28 61 573366 4.85 ug/L 99 17) 1,1-DICHLOROETHANE 11.17 63 687709 4.71 ug/L 100 18) 2-BUTANONE (MEK) 12.00 43 72009 3.28 ug/L 93 19) 2,2-DICHLOROPROPANE 12.40 77 561315 5.21 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.48 96 410409 4.57 ug/L 98 21) CHLOROFORM 12.82 83 768726 5.01 ug/L 98 22) BROMOCHLOROMETHANE 13.20 49 297910 3.94 ug/L 89 23) 1,2-DICHLOROETHANE 14.54 62 522780 5.39 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.71 97 587198 5.78 ug/L 97 27) 1,1-DICHLOROPROPENE 14.03 75 548445 5.51 ug/L 98 28) CARBON TETRACHLORIDE 14.30 117 510151 5.98 ug/L 99 29) BENZENE 14.64 78 1372121 4.87 ug/L 98 30) TRICHLOROETHENE 15.90 95 439564 5.30 ug/L 98 31) 1,2-DICHLOROPROPANE 16.26 63 350188 4.28 ug/L 99 32) DIBROMOMETHANE 16.94 174 204897 4.78 ug/L 95 33) BROMODICHLOROMETHANE 16.79 83 534561 5.21 ug/L 97 34) 2-CHLOROETHYL VINYL ETHER 17.26 63 111389 4.29 ug/L 89 35) METHYL ISO-BUTYL KETONE 17.35 58 50661 3.48 ug/L 95 36) CIS-1,3-DICHLOROPROPENE 17.88 75 504447 4.52 ug/L 98 37) TOLUENE 18.63 91 1524373 4.92 ug/L 100 3 8) TRANS-1,3-DICHLOROPROPENE 18.90 75 398014 4.99 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.29 97 245761 4.62 ug/L 98 40) TETRACHLOROETHENE 20.07 166 454167 5.11 ug/L 96 41) 1,3-DICHLOROPROPANE 19.82 76 434878 4.46 ug/L 99 42) DIBROMOCHLOROMETHANE 20.52 129 310804 4.87 ug/L 99 43) 1,2-DIBROMOETHANE 20.96 107 242152 4.47 ug/L 99 44) CHLOROBENZENE 21.84 112 1008948 4.75 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.90 131 357640 5.08 ug/L 97 46) 2-HEXANONE 19.19 43 98476 2.65 ug/L 100 47) ETHYLBENZENE 21.88 91 1810460 5.15 ug/L 100 48) P & M-XYLENE 22.05 106 1255609 9.91 ug/L 91 (#) = qualifier out of range (m) = manual integration 0314R5A.D HP022702.M Thu Mar 14 12:39:07 2002 Page 1

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