Volatile organic compounds results, Mar 13 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02MAR13\0313R5.D Vial: 4 Acq On : 13 Mar 2002 11:21 am Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 14 11:20 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Mar 13 14:51:22 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.09 114 1799265 5.00 ug/L -0.09 24) CHLOROBENZENE-D5 21.74 117 1706438 5.00 ug/L -0.09 52) l/4-DICHLOROBENZENE-D4 26.94 152 895855 5.00 ug/L -0.07 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 749202 6.44 ug/L -0.09 Spiked Amount 5.000 Recovery = 128.80% 3) 4-BROMOFLUOROBENZENE 24.33 174 689555 4.73 ug/L -0.09 Spiked Amount 5.000 Recovery = 94.60% 25) TOLUENE-D8 18.44 98 2162502 5.26 ug/L -0.09 Spiked Amount 5.000 Recovery = 105.20% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.87 85 266329 5.60 ug/L 100 5) CHLOROMETHANE 5.47 50 305916 5.83 ug/L 99 6) VINYL CHLORIDE 5.60 62 241079 7.00 ug/L 98 7) BROMOMETHANE 6.58 94 194447 6.03 ug/L 90 8) CHLOROETHANE 6.71 64 198568 6.80 ug/L 98 9) TRICHLOROFLUOROMETHANE 7.28 101 409678 6.21 ug/L 98 12) ACETONE 8.24 43 70468 7.65 ug/L 90 13) 1,1-DICHLOROETHENE 8.60 61 413834 5.28 ug/L 94 14) METHYLENE CHLORIDE 9.60 49 406084 4.40 ug/L 95 15) METHYL TERT BUTYL ETHER 9.91 73 431142 4.07 ug/L 95 16) TRANS-1,2-DICHLOROETHENE 10.27 61 456900 4.30 ug/L 98 17) 1,1-DICHLOROETHANE 11.15 63 543676 4.14 ug/L 97 18) 2-BUTANONE (MEK) 12.00 43 58783 2.98 ug/L 88 19) 2,2-DICHLOROPROPANE 12.38 77 431759 4.46 ug/L 98 20) CIS-1,2-DICHLOROETHENE 12.46 96 339820 4.21 ug/L 97 21) CHLOROFORM 12.80 83 604614 4.39 ug/L 97 22) BROMOCHLOROMETHANE 13.18 49 243527 3.59 ug/L 95 23) 1,2-DICHLOROETHANE 14.52 62 426060 4.89 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.71 97 463712 5.08 ug/L 97 27) 1,1-DICHLOROPROPENE 14.03 75 435993 4.87 ug/L 99 28) CARBON TETRACHLORIDE 14.29 117 402575 5.26 ug/L 96 29) BENZENE 14.63 78 1100710 4.35 ug/L 98 30) TRICHLOROETHENE 15.89 95 348660 4.68 ug/L 95 31) 1,2-DICHLOROPROPANE 16.26 63 283410 3.86 ug/L 97 32) DIBROMOMETHANE 16.92 174 160618 4.17 ug/L 98 33) BROMODICHLOROMETHANE 16.77 83 430179 4.67 ug/L 95 34) 2-CHLOROETHYL VINYL ETHER 17.25 63 88211 3.79 ug/L 96 35) METHYL ISO-BUTYL KETONE 17.33 58 39079 2.99 ug/L 92 36) CIS-1,3-DICHLOROPROPENE 17.86 75 408892 4.08 ug/L 99 37) TOLUENE 18.63 91 1220332 4.39 ug/L 98 3 8) TRANS-1,3-DICHLOROPROPENE 18.90 75 322274 4.50 ug/L 96 39) 1,1,2-TRICHLOROETHANE 19.29 97 195495 4.09 ug/L 98 40) TETRACHLOROETHENE 20.07 166 354757 4.44 ug/L 99 41) 1,3-DICHLOROPROPANE 19.82 76 352059 4.02 ug/L 99 42) DIBROMOCHLOROMETHANE 20.50 129 248968 4.34 ug/L 100 43) 1,2-DIBROMOETHANE 20.96 107 196021 4.03 ug/L 94 44) CHLOROBENZENE 21.85 112 814399 4.27 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.88 131 287277 4.54 ug/L 97 46) 2-HEXANONE 19.19 43 83357 2.50 ug/L 91 47) ETHYLBENZENE 21.88 91 1435500 4.55 ug/L 98 48) P & M-XYLENE 22.03 106 999625 8.79 ug/L 93 (#) = qualifier out of range (m) = manual integration 0313R5.D HP022702.M Fri Mar 15 14:56:51 2002 Page 1

NYC-WTC_000021639