Volatile organic compounds results, Mar 10 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed)

Data File : C:\HPCHEM\1\DATA\02mar10\0310R5.D Vial: 6 Acq On : 10 Mar 2002 1:08 pm Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 10 13:46 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.09 114 1489925 5.00 ug/L -0.09 24) CHLOROBENZENE-D5 21.74 117 1429427 5.00 ug/L -0.09 52) 1,4-DICHLOROBENZENE-D4 26.93 152 739533 5.00 ug/L -0.07

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 622327 6.46 ug/L -0.09 Spiked Amount 5.000 Recovery = 129.20% 3) 4-BROMOFLUOROBENZENE 24.33 174 554135 4.59 ug/L -0.09 Spiked Amount 5.000 Recovery = 91.80% 25) TOLUENE-D8 18.44 98 1806513 5.24 ug/L -0.09 Spiked Amount 5.000 Recovery = 104.80%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.86 85 143267 3.72 ug/L 96 5) CHLOROMETHANE 5.49 50 174696 4.06 ug/L 95 6) VINYL CHLORIDE 5.60 62 165358 6.54 ug/L 95 7) BROMOMETHANE 6.58 94 170383 6.34 ug/L 94 8) CHLOROETHANE 6.71 64 179715 7.40 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.28 101 325262 5.95 ug/L 99 12) ACETONE 8.24 43 60323 7.91 ug/L 93 13) 1,1-DICHLOROETHENE 8.60 61 345975 5.33 ug/L 97 14) METHYLENE CHLORIDE 9.60 49 462309 6.05 ug/L 97 15) METHYL TERT BUTYL ETHER 9.91 73 433809 4.95 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.27 61 432383 4.92 ug/L 97 17) 1,1-DICHLOROETHANE 11.15 63 552138 5.08 ug/L 99 18) 2-BUTANONE (MEK) 11.99 43 64845 3.97 ug/L 87 19) 2,2-DICHLOROPROPANE 12.38 77 439167 5.48 ug/L 100 20) CIS-1,2-DICHLOROETHENE 12.46 96 348794 5.22 ug/L 99 21) CHLOROFORM 12.80 83 629306 5.51 ug/L 98 22) BROMOCHLOROMETHANE 13.18 4'9 257546 4.58 ug/L 91 23) 1,2-DICHLOROETHANE 14.52 62 414835 5.75 ug/L 97 26) 1,1,1-TRICHLOROETHANE 13.69 97 461044 6.03 ug/L 98 27) 1,1-DICHLOROPROPENE 14.01 75 454072 6.06 ug/L 98 28) CARBON TETRACHLORIDE 14.29 117 387435 6.04 ug/L 98 29) BENZENE 14.63 78 1044574 4.93 ug/L 99 30) TRICHLOROETHENE 15.89 95 329652 5.29 ug/L 98 31) 1,2-DICHLOROPROPANE 16.24 63 286128 4.65 ug/L 100 32) DIBROMOMETHANE 16.92 174 146816 4.55 ug/L 93 33) BROMODICHLOROMETHANE 16.77 83 413206 5.35 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.25 63 93528 4.79 ug/L 96 35) METHYL ISO-BUTYL KETONE 17.33 58 42420 3.87 ug/L 92 36) CIS-1,3-DICHLOROPROPENE 17.86 75 408633 4.87 ug/L 99 37) TOLUENE 18.61 91 1204672 5.17 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.90 75 320544 5.34 ug/L 100 39) 1,1,2-TRICHLOROETHANE 19.27 97 194630 4.86 ug/L 97 40) TETRACHLOROETHENE 20.06 166 335025 5.01 ug/L 96 41) 1,3-DICHLOROPROPANE 19.80 76 357760 4.88 ug/L 99 42) DIBROMOCHLOROMETHANE 20.50 129 240393 5.00 ug/L 98 43) 1,2-DIBROMOETHANE 20.96 107 193294 4.74 ug/L . 96 44) CHLOROBENZENE 21.83 112 813275 5.09 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.88 131 278425 5.26 ug/L 97 46) 2-HEXANONE 19.17 43 81164 2.91 ug/L 96 47) ETHYLBENZENE 21.88 91 1464420 5.54 ug/L 98 48) P & M-XYLENE 22.03 106 1008237 10.58 ug/L 93

(#) = qualifier out of range (m) = manual integration 0310R5.D HP022702.M Sun Mar 10 13:46:59 2002 Page 1

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