Volatile organic compounds results, Mar 6 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02mar06\0306R5A.D Vial: 5 Acq On : 6 Mar 2002 11:40 am Operator: 201-wb Sample : ref 5 Inst : GC/MS Ins Mise : March 6, 2002 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 6 12:18 2002 Quant Results File: HP022702.RES

Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.07 114 1801887 5.00 ug/L -0.10 24) CHLOROBENZENE-D5 21.72 117 1816625 5.00 ug/L -0.10 52) 1,4-DICHLOROBENZENE-D4 26.90 152 898440 5.00 ug/L -0.10 System Monitoring. Compounds 2) 1,2-DICHLOROETHANE-D4 14.30 65 706141 6.06 ug/L -0.10 Spiked Amount 5.000 Recovery = 121.20% 3) 4-BROMOFLUOROBENZENE 24.31 174 674277 4.62 ug/L -0.10 Spiked Amount 5.000 Recovery = 92.40% 25) TOLUENE-D8 18.42 98 2266313 5.17 ug/L -0.10 Spiked Amount 5.000 Recovery = 103.40% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 262646 5.52 ug/L 99 5) CHLOROMETHANE 5.47 50 239687 4.59 ug/L 96 6) VINYL CHLORIDE 5.59 62 172049 5.49 ug/L 95 7) BROMOMETHANE 6.56 94 157633 5.01 ug/L 91 8) CHLOROETHANE 6.70 64 148238 5.17 ug/L 95 9) TRICHLOROFLUOROMETHANE 7.25 101 276998 4.19 ug/L 97 12) ACETONE 8.22 43 51019 5.53 ug/L 97 13) 1,1-DICHLOROETHENE 8.58 61 411750 5.25 ug/L 97 14) METHYLENE CHLORIDE 9.59 49 508415 5.50 ug/L 99 15) METHYL TERT BUTYL ETHER 9.89 73 446441 4.21 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.25 61 470226 4.42 ug/L 99 17) 1,1-DICHLOROETHANE 11.13 63 579564 4.41 ug/L 99 18) 2-BUTANONE (MEK) 11.97 43 63369 3.21 ug/L 89 19) 2,2-DICHLOROPROPANE 12.36 77 431288 4.45 ug/L 98 20) CIS-1,2-DICHLOROETHENE 12.45 96 352863 4.36 ug/L 95 21) CHLOROFORM 12.79 83 606656 4.40 ug/L 100 22) BROMOCHLOROMETHANE 13.16 49 282705 4.16 ug/L 94 23) 1,2-DICHLOROETHANE 14.51 62 424380 4.87 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.67 97 441590 4.54 ug/L 99 27) 1,1-DICHLOROPROPENE 13.99 75 456373 4.79 ug/L 97 28) CARBON TETRACHLORIDE 14.25 117 367027 4.50 ug/L 99 29) BENZENE 14.59 78 1217572 4.52 ug/L 100 30) TRICHLOROETHENE 15.87 95 358935 4.53 ug/L 97 31) 1,2-DICHLOROPROPANE 16.23 63 333985 4.27 ug/L 98 32) DIBROMOMETHANE 16.91 174 152980 3.73 ug/L 90 33) BROMODICHLOROMETHANE 16.75 83 435065 4.43 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 105344 4.25 ug/L 100 35) METHYL ISO-BUTYL KETONE 17.31 58 50029 3.59 ug/L 92 36) CIS-1,3-DICHLOROPROPENE 17.84 75 462582 4.34 ug/L 98 37) TOLUENE 18.59 91 1338813 4.52 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.86 75 353589 4.63 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.26 97 219325 4.31 ug/L 99 40) TETRACHLOROETHENE 20.04 166 343802 4.04 ug/L 97 41) 1,3-DICHLOROPROPANE 19.78 76 398510 4.27 ug/L 98 42) DIBROMOCHLOROMETHANE 20.48 129 249885 4.09 ug/L 99 43) 1,2-DIBROMOETHANE 20.92 107 212343 4.10 ug/L 99 44) CHLOROBENZENE 21.81 112 875848 4.32 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.86 131 286883 4.26 ug/L 99 46) 2-HEXANONE 19.15 43 90730 2.56 ug/L 96 47) ETHYLBENZENE 21.84 91 1599578 4.76 ug/L 98 48) P & M-XYLENE 22.00 106 1081948 8.93 ug/L 95 (#) = qualifier out of range (m) = manual integration 0306R5A.D HP022702.M Wed Mar 06 12:18:47 2002 Page 1

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