Volatile organic compounds results, Mar 14 2002

NYC 9/11 Public Portal Document

Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02mar14\0314C10A.D Vial: 2 Acq On : 14 Mar 2002 9:02 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 14 21:40 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Mar 13 14:51:22 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.08 114 1184993 5.00 ug/L -0.09 24) CHLOROBENZENE-D5 21.74 117 1087423 5.00 ug/L -0.09 52) 1,4-DICHLOROBENZENE-D4 26.93 152 548303 5.00 ug/L -0.07 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 484874 6.33 ug/L -0.09 Spiked Amount 5.000 Recovery = 126.60% 3) 4-BROMOFLUOROBENZENE 24.33 174 438945 4.58 ug/L -0.09 Spiked Amount 5.000 Recovery = 91.60% 25) TOLUENE-D8 18.44 98 1399449 5.34 ug/L -0.09 Spiked Amount 5.000 Recovery = 106.80% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 391945 11.66 ug/L 98 5) CHLOROMETHANE 5.45 50 415731 11.64 ug/L 97 6) VINYL CHLORIDE 5.59 62 299221 13.20 ug/L 92 7) BROMOMETHANE 6.58 94 303739 13.38 ug/L 98 8) CHLOROETHANE 6.71 64 278789 14.07 ug/L 95 9) TRICHLOROFLUOROMETHANE 7.26 101 549485 12.64 ug/L 100 12) ACETONE 8.24 43 72201 11.91 ug/L 95 13) 1,1-DICHLOROETHENE 8.60 61 543581 10.53 ug/L 99 14) METHYLENE CHLORIDE 9.60 49 505113 8.30 ug/L 93 15) METHYL TERT BUTYL ETHER 9.89 73 965290 13.85 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.27 61 581523 8.31 ug/L 99 17) 1,1-DICHLOROETHANE 11.15 63 688959 7.97 ug/L 99 18) 2-BUTANONE (MEK) 11.99 43 65116 5.01 ug/L— 85 19) 2,2-DICHLOROPROPANE 12.38 77 514494 8.08 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.46 96 426571 8.02 ug/L 96 21) CHLOROFORM 12.80 83 790842 8.71 ug/L 98 22) BROMOCHLOROMETHANE 13.18 49 297987 6.66 ug/L— 92 23) 1,2-DICHLOROETHANE 14.52 62 544310 9.49 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.69 97 603199 10.37 ug/L 99 27) 1,1-DICHLOROPROPENE 14.03 75 553213 9.71 ug/L 98 28) CARBON TETRACHLORIDE 14.28 117 528657 10.83 ug/L 97 29) BENZENE 14.62 78 1382609 8.58 ug/L 98 30) TRICHLOROETHENE 15.90 95 440578 9.29 ug/L 96 31) 1,2-DICHLOROPROPANE 16.26 63 353374 7.55 ug/L 97 32) DIBROMOMETHANE 16.92 174 205231 8.36 ug/L 97 33) BROMODICHLOROMETHANE 16.77 83 544676 9.27 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.25 63 111160 7.49 ug/L 100 35) METHYL ISO-BUTYL KETONE 17.33 58 52520 6.30 ug/L— 86 36) CIS-1,3-DICHLOROPROPENE 17.86 75 499467 7.82 ug/L 98 37) TOLUENE 18.63 91 1535035 8.66 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.90 75 395064 8.65 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.29 97 247284 8.12 ug/L 96 40) TETRACHLOROETHENE 20.07 166 449033 8.82 ug/L 97 41) 1,3-DICHLOROPROPANE 19.82 76 441819 7.91 ug/L 98 42) DIBROMOCHLOROMETHANE 20.50 129 318806 8.72 ug/L 99 43) 1,2-DIBROMOETHANE 20.96 107 246975 7.96 ug/L 95 44) CHLOROBENZENE 21.83 112 1004251 8.27 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.88 131 362449 9.00 ug/L 95 46) 2-HEXANONE 19.17 43 92889 4.38 ug/L 99 47) ETHYLBENZENE 21.88 91 1800514 8.95 ug/L 99 48) P & M-XYLENE 22.03 106 1218079 16.80 ug/L 95 (#) = qualifier out of range (m) = manual integration 0314C10A.D HP022702.M Thu Mar 14 21:40:47 2002 Page 1

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