GCMS sample analysis results, Jan 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\DEC2701\30256.D Vial: 17 Acq On : 29 Dec 2001 2:47 pm Operator: 209 GALOS Sample : GC/MS SCAN Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

21.03 2.12 ug/1 798829 Acenaphthene-dl0 20.56

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzoic acid/ 4-ethoxy-, ethyl este 194 C11H1403 023676-09-7 96 2 ortho-Hydroxypropiophenone 150 C9H10O2 000610-99-1 43 3 Benzoic acid, 2-hydroxy-, hydrazide 152 C7H8N2O2 000936-02-7 43 4 Acetic acid, (benzoylamino)hydroxy- 195 C9H9N04 _ 016555-77-4 40 Abundance Scan 1741 (21.029 mln): 30256.D (-) m/z 120.90 100.00%

5000

m/z-> 0 mpmmhmHm| 50 39 ,, 76 85 . 121

109 65 1 11,117% .. I' ... :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 93 20.60 20.80 21.00 21.20 21.40 m/z 149.00 47.54% 138 149

166 194 . X_ - । । i-i । i i 1 i । । i |TT i 1 | i i ,

Abundance #21260: Benzoic acid, 4-ethoxy-, ethyl ester 121

5000 138 149

194 0 TT" 1 I 20.60 20.80 21.00 21.20 21.40 65 93 166 m/z 194.05 28.15% 27 | 11... I.... 1.... I Utt T m/z-> : Abundancei k I ‘ * । * I' । ‘ ‘ l ‘ rrrfj. r. p '**1****) 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #9726; ortho-Hydroxypropiophenone I ’4 “ I ‘“ I ‘ '1 i

121 I ' ■ ’ ‘ I ' 1 ‘ ‘ I ‘ ' 20.60 20.80 21.00 21.20 21.40 5000 m/z 138.05 26.70% 150 65 93 27 77 131 4 j I I I I J I I I I | I i > I | > I < S | « i I I | I I <1 | l I i I j l ( > I j l l t | t < H | I I I I | I I I I | I I M I | i i i < | i > I i j i i > i । » i i « । i i

miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #10124: Benzoic acid, 2-hydroxy-, hydrazide I * * >1111 ■ ITFTTTT ; 121 L 20.22% 20.60 20.80 21.00 21.20 21.40 m/z 5000 65 93 152 37 53 , 111111:|Ji i. ।।f . I.... i.... i.... i.... 1111 * i1 * .. Tn TTTpTTT miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.60 20.80 21.00 21.20 21.40

30256.D GCMS1126.M Wed Jan 02 10:24:39 2002 Page 7

NYC-WTC_000019143