GCMS analysis summary, sample AD27288, Dec 2001

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\JAN0 802\27288.D Vial: 26 Acq On 9 Jan 2002 3:42 pm Operator: 209 GALOS Sample gems scan 12/20a Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

20.86 2.25 ug/1 752340 Acenaphthene-dl0 20.39

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, 4-ethoxy-, ethyl este 194 C11H14O3 023676-09-7 97 2 Benzoic acid, 2-hydroxy-, hydrazide 152 C7H8N2O2 000936-02-7 43 3 ortho-Hydroxypropiophenone 150 C9H10O2 000610-99-1 43 4 Phenol, 4 - fomylcarbonyl - 150 C8H6O3 __ 000000-00-0 43 Abundance Scan 1722 (20.855 min): 27288.D (-) m/z 120 .95 1 00.00% 121

5000

■ i' ■1 ■ i ■ 65 93 39 50 , 77 if 109 111•■ • । * mHmtpmto 138 149

166 179 H . 194a . 20.60 20.80 21.00 21.20 m/z 149.00 48.47% miz-2.__ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #69400”: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 5000 194 138 20.60 20.80 21.00 21.20 65 93 166 m/z 194.05 2 9.30% .... 50. . 76 . 11... ।.... j n J11....(′**.।. ■ 1 •1 • 11 ‘ “ I * ’ “ I ’41 * I ‘ ‘I““I‘ " i“ m/z-> 20 Abundancei : 30 40 50 60 #10124. 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Benzoic acid. 2-ivdrom- hydrazide 121 20.60 20.80 21.00 21.20 5000 m/z 138.05 27.73% 65 93 152 37 53 miz-> 20 : 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance‘ #9726: ortho-Hydroxypropiophenone T T I 1 ‘ ‘ ‘ I ‘ ‘ 121 20.60 20.80 21.00 21.20 m/z 65.05 20.23% 5000 65 150 93 27 77 TIWmpp’n ।.... ।.... । r.| .. ।....!.... । । 131 ....।.... ।.... ।.... ।.... ।.. Arns ... Pp pi i | r i m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.60 20.80 21.00 21.20

27288.D GCMS1126.M Mon Feb 04 15:23:18 2002 Page 7

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