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GC/MS analysis results for sample AD30934, Jan 28 2002

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Laboratory report documenting gas chromatography mass spectrometry results for sample AD30934 conducted on January 28, 2002.

NYC-WTC_000018733–000018753

Folder label: “GCMS X 12/19/01 A 1/2/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C: \HPCHEM\ 1 \DATA\DEC3101\30934.D Vial: 51 Acq On 2 Jan 2002 3:21 pm Operator: 209 GALOS Sample gems scan 12/19a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

21.07 1.51 ug/1 517827 Acenaphthene-dl0 20.56

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid, 4-ethoxy-, ethyl este 194 C11H14O3 023676-09-7 91 2 Benzenepropanoic a d, 4-methoxy-. 194 C11H14O3 015823-04-8 43 3 Benzoic acid, ethoxy-, ethyl ester 194 C11H14O3 075333-22-1 38 4 Benzoic acid, 4-ethoxy- 166 C9H10O3 000619-86-3 38 Abundance Scan 1745 (21.067 mln): 30934.D (-) m/z 120.95 100.00% 121

5000 149 138 194 65 93 1*/T/*12//*1////-1/5m///1/2/B.8.3 39 166

miz-> m irrejilego/ 76 85 ll TTT +4179— 50 50 rihi 109 | ■ ■ i • ■

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.80 21.00 21.20 21.40 m/z 149.00 48.75% Abundance #69400: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 / 5000 194 T Tit TT T “i 138 20.80 21.00 21.20 21.40 65 m/z 194.05 29.87%

.k 93 166 ....50. 1 76 ,| j...r J . H.j .... j .... j ... f j i .।.j.... 11...]... i j.... । “ i' ■ miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #21262; Benzenepropanoic acid, 4-methoxy- methyl ester 121 20.80 21.00 21.20 21.40 5000 m/z 138.0 25.83% 194 134 I.... I 108 151 163 ; 111111111111111111111...1111... I.... I.... 1(.in1ni. |. i|. m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #21246: Benzoic add, ethoxy-, ethyl ester ...... p 121 20.80 21.00 21.20 21.40 m/z 65.05 19.43% 138 5000 194 29 65 149 i 39 93 | 166 I ___ । 1 Ppu ।. r.. । । ।।. “i" miz—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200

30934.D GCMS1126.M Fri Jan 25 11:46:59 2002 Page 7

NYC-WTC_000018746

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