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GC/MS analysis results for sample AD30907, Jan 28 2002

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Laboratory report documenting gas chromatography mass spectrometry results for sample AD30907 conducted on January 28, 2002.

NYC-WTC_000018664–000018683

Folder label: “GCMS X 12/19/01 A 1/2/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C: \HPCHEM\ 1 \DATA\ DEC3101\30907.D Vial: 43 Acq On 2 Jan 2002 5:37 am Operator: 209 GALOS Sample gems scan 12/19a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

21.08 1.19 ug/1 340646 Acenaphthene-dl0 20.56

Hit# of 5 Tentative ID MW MolForm CAS# Qual

>1 Benzoic acid, 4-ethoxy-, ethyl este 194 C11H1403 023676-09-7 96 2 Benzehepropanoic acid, 4-methoxy-, 194 C11H1403 015823-04-8 43 3 1-Cyclopentene-1-propanoic acid. .b 168 C1OH1602 4 Ethyl 3-hydroxyb zoate ‘Abundance 166 C9H10O3 ....... .S Scan 1747 (21.085 min): 30907.D (-) 121 " 57 061833-30-5 38 007781-98-8 38

5000 149 138 194 65 93 39 166 20.80 21.00 21'20 21.40 miz-> T 50 . .76 85 I, 158 l 104 | 179 TWTWIPWTNTTTTTTTTTTT ■ i “ ■ ■ i j j rgr’i’s rt’r’s । ill*! ′ Ml’r’ra’uu IH 1'1*1 x*| > * * * j ‘ I‘* :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 I m/z 149.00 44.06% Abundance! #21260: Benzoic acid, 4-ethoxy-, ethyl ester 111 ....... __ 149 5000 138 20.80 21.00 21.20 21.40 194 65 93 166 m/z 194.05 28.42% 27 I . ] . . . . ,... |! >...,... . ।. i,.. .. 11...।.... 1.... 11... 1... ।.... ।.... ।..1.1.. n ।.... ।. ’ I’’ m/z-> :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance। ’ #21262: Benzenepropanoic acid, 4-methoxy- methyl ester 111 • ‘ I ' ' A.. 20.80 21.00 21.20 21.40 5000 m/z 137.95 25.53% 194 134 i 108 151 163 m/z-> Abundance 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #14561:1-Cyclopentene-1-propanoic acid, .beta.-methyl-, me . r 58 79 95 121 20.80 21.00 21.20 21.40 8000 m/ z 64.95 19.73% 109 6000

4000 150

I" “ J *1 “1 ’ ’’1* ’ ’ I * “ I ‘ “ ‘I mmpo— 168 /Sa r-r-r-j-r-r miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.80 21.00 21,20 21.40

30907.D GCMS1126.M Fri Jan 25 11:35:52 2002 Page 7

NYC-WTC_000018677

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