GCMS analysis results for unknown compounds, June 2002

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Data File C:\MSDCHEM\l\DATA\060702\12736.D Vial: 12 Acq On 7 Jun 2002 5:32 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library- : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 13 Phenanthrene, 1-methyl- Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

22.53 0.27 ug/L 288475 Phenanthranene-dl0 22.91

Hit# of 5 Tentative ID MW MolForm CAS# Qual 0 1 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 53 2 Phenanthrene, 4-methyl- 192 C15H12 000832-64-4 50 • 3 2,5-Dihydrophosphole, 3-methyl-l... 192 C11H13OP 1000196-97-5 45 4 Anthracene, 9-methyl- 192 C15H12 000779-02-2 42 Abundance Scan 3311 (22.533 min): 12736. D (-3294) (-) m/z 192.10 100.00% 1912

5000 / ......... 146 160 40 51 70 82 96 118 | 22.20 22.40 22.60 22.80 0 TPTTTTYL ala rI‘ ■.. 11 ■ 111 ■ ■ 111111111H । mHmmmtp m/z 191.00 21.06% miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- 192

5000 22.20 22.40 22.60 22.80 m/z 193.00 17.91% 96 EE /z-> 27 39 51 63 82 ll 115 126 139 152 190 178 1 4 0 ' i" " i" ■ ■ i ■ ■ “ 11 ■" 1'1 “ I ■ri ■ i’1 • "1 ■ 11 ‘ । ■ 11 i'll 11111 > । ■ 111'| 1111 |'i 1111 i'i'i 1111 i'l| 11 i’r 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125851: Phenanthrene, 4-methyl- 102 ’I 22.20 22.40 22.60 22.80 5000 m/z 146.00 15.98% fl 40 95 165 „5P.3. 01 ‘ I “ *' I * ’ 82 | 125 139 152 I 174 . r i'!1, 'I' Al । > ■ 111111111 MI’ 1111 ′ 111 fl 11111‘I1 > 11 ■ 11111 " i i miz-> Abundance 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #80965: 2,5-Dihydrophosphole, 3-methyl-1-oxo-1-phenyI- 192 22.20 22.40 22.60 22.80 11 164 m/z 96.10 11.20%

5000 99 115 47 77 177 67 125,2 146 m/z—> 0 +.27,381,1114.57,,+H7+44,4155, p+ r ‘I’T 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 ‘I

12736.D 060302.M Mon Jun 10 11:23:34 2002 Page 16

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