GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Llorary searen compound Keporc Data File : C:\MSDCHEM\l\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 17 Phenanthrene, 9-methyl- Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T. 22.54 0.26 ug/L 268704 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53 2 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5/45 3 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42 4 2-Imidazolidinone, 1-methoxy-3-p... 192 C10H12N2O2 052420-43-6 38 Abundance Scan 3311 (22.533 min): 12287.D (-3303) (-) m/z 192.10 100.00% 192

5000

41 66 82 96 146 160 22.20 22.40-22.60 22.80 0mmmphpp 118 PHH —mm m/z 191.00 18.96% miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 1512

5000 22 20 22.40 22.60 22.80 m/z 193.10 13.64 29 39 51 63 74 83 * 115 126 139 152 165 176 0- ।,... ।. j ....,. i., । A ., ।. ri. [ i-l'i 1111 j i > 111 m 111 n-r| 1111-|, 111 |-t 11 > । i'i'i 111 H-r II niz-> 20 30 40 50 60 70 80 90 100110120130140150160170180190200 Abundance #80950:1,5-Naphthalenedithiole 192 T T T T 22.20 22.40 22.60 22.80 5000 m/z 146.10 13.61%I 115 128 159 40 57 69 79 96 147

n/z—> 0 r 1196 illp v IM 20 30 40 50 60 70 80 90 100 110120 130 140 150 160170 180190 200 —177 ‘ I Abundance #80953:2-Propenal, 3-(3,4-dimethoxyphenyl)- — A 192 22.20 22.40 22.60 22.80 161 m/z 96.00 13.52 5000 77 91 103 121 149 177 0‘ 52 64 pl I>|UU "" ,-l | 14 I l | u J -[ 138 । “' ■ T 1I n/z—> 2030405060 70 8090 100110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

12287.D 052202.M Thu May 30 10:40:35 2002 Page 20

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