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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE12287 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000014004–000014032

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Library Searcn compound. Report Data File : C:\MSDCHEM\l\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 18 Anthracene-dlO- Concentration Rank 16

R.T. EstConc Area Relative to ISTD R.T. 23.06 0.31 ug/L 320148 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene-diO- 188 C14D10 001719-06-8 86 9 2 Phenanthrene-diO 188 C14D10 001517-22-2 78— 3 2-Quinolinecarboxaldehyde, 8-hyd... 188 C10H8N2O2 005603-22-5 42 4 Naphthalene, 1,7-dimethoxy- 188 C12H1202 005309-18-2 36 Abundance Scan 3401 (23.062 min): 12287.D (-3394) (-) m/z 188.16 100.00% 188

5000

80 94 43 57 66 , 158 22.80 23.00 23.20 23.40 0 TCImmTTT .. 111.. ।..., ।.... ।.... ।132 i.. - m/z 189.10 17.85% miz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190 Abundance #79826: Anthracene-d10- 11®

5000 ,.sa . . ....... 22.80 23.00 23.20 23.40 m/z 94.10 14.88% 80 94 160 , 17 30 42 52 0 .1 J 108118 132. 146 II 170179.,। 0- I r 111 n U I U 1111111111II1111 11 n I f 1111 r| 1111111 ij 111111 11 111 II 1111111111 ‘ ‘ 111 [ I n I MIttri 11 miz-> 10 20 30 40 50 60 70 80 90 100110120130140150 160170180190 Abundance। #79827: Phenanthrene-d10 188 .................................................. 22.80 23.00 23.20 23.40 5000 m/z 80.10 13.57%

80 94 160 30 42 52 66 . 108118 132 146 ,|. 170179,1 11 TT 0-TIPTTmTTTTTTTTTH— mlz-> 10 2030405060 70 8090 100110120 130140150160170180190 Abundance #125696:2-Quinolinecarboxaldehyde, 8-hydroxy-, oxime ............... 188 22.80 23.00 23.20 23.40 m/z 184.10 13.25% 5000 143 . 89 115 64 76 | 102 . 130 । 158 170 miz-> 0 m -HHH— 51 mm Tour 10 2030405060 70 8090 100110120130140150160170180190 m 22.80 23.00 23.20 23.40

12287.D 052202.M Thu May 30 10:40:37 2002 Page 21

NYC-WTC_000014029

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NYC-WTC_000014029Source: NYC Law Department, mirrored locally

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