GCMS calibration data AE11284, DEP Labs, May 2002

NYC 9/11 Public Portal Document . Library Search Compound Report Data File : C:\HPCHEM\1\DATA\MAY3002\12095.D Vial: 14 Acq On : 31 May 2002 2:51 am Operator: Morgan Sample : re-ext Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Phenanthrene-diO Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T. 25.57 0.47 ug/1 50013 Phenanthrene-dl0 25.43 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene-diO 188 C14D10 001517-22-2 72 2 Anthracene-d10- 188 C14D10 001719-06-8 43 3 4-Methyl-2-(4-fluorophenyl)pyrimidi 188 C11H9FN2 076128-67-1 40 4 Cyclohexanone, phenyl hydra zone 188 C12H16N2: 000946-82-7 9 Abundance Scan 2236 (25.569 min): 12095.D (-) m/z 188.10 100.00% 1118

5000

80 94 TBndmmuTRTTT 25.20 25.40 25.60 25.80

iz-> 42 54 66 ‘ ■ i ■ ■ ■ ■ i" ■ ■ 1111 ■ i “'1 TH TT 1’8 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 158 । L m/z 189.10 19.90% Abundance #19958: Phenanthrene-d10 118

5000 . । > . . . । .T . r-| . . । , । । । ! । । । 25.20 25.40 25.60 25.80 m/z 79.95 16.96% 80 94 160 66 pnongmarl — ----- - •।■■■■ । ■ miz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19957: Anthracene-d10- 1)18

25.20 25.40 25.60 25.80 5000 m/z 93.90 14.72%

8094 160 Hr.... rH.... I ""ill' H mz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19860:4-Methyl-2-(4-fluorophenyl)pyrimidine -------- 118 25.20 25.40 25.60 25.80 m/z 184.05 13.15% 121 5000 173

m/z—> .......... 57 | 75 67 94 |,102 ■ ‘ i " ■ ■ i' ■ ■ ■ i “ 1 ■ i" " i11" i ■1" i" 1' i " ' 146 + " i • “ ■ i1 ■1 ■ i"' • i" " i'

40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 j_____ ITTT 25.20 25.40 25.60 25.80

12095.D GCMS0520.M Fri May 31 11:34:40 2002 Page 3

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